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N-(3-Methyl­phen­yl)benzamide

The asymmetric unit of the title compound, C(14)H(13)NO, contains four mol­ecules, which are linked through N—H⋯O hydrogen bonds into two symmetry-independent chains running parallel to [001] and [101]. The N—H and C=O bonds of the amide groups are trans oriented in all four mol­ecules. The mol­ecul...

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Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Sowmya, B. P., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959694/
https://www.ncbi.nlm.nih.gov/pubmed/21581101
http://dx.doi.org/10.1107/S1600536808035186
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author Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The asymmetric unit of the title compound, C(14)H(13)NO, contains four mol­ecules, which are linked through N—H⋯O hydrogen bonds into two symmetry-independent chains running parallel to [001] and [101]. The N—H and C=O bonds of the amide groups are trans oriented in all four mol­ecules. The mol­ecules are not planar and both aromatic rings are twisted strongly relative to the plane of the amide group. The dihedral angle between the two benzene rings ranges from 70.6 (2) to 74.2 (2)°. The N—H bond is anti to the meta-methyl substituent in the aniline fragment in three of the four symmetry-independent mol­ecules. In the fourth mol­ecule, the aniline unit is disordered over two nearly coplanar positions; the anti and syn conformers occupy the same site in the crystal with equal probability.
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spelling pubmed-29596942010-12-30 N-(3-Methyl­phen­yl)benzamide Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(14)H(13)NO, contains four mol­ecules, which are linked through N—H⋯O hydrogen bonds into two symmetry-independent chains running parallel to [001] and [101]. The N—H and C=O bonds of the amide groups are trans oriented in all four mol­ecules. The mol­ecules are not planar and both aromatic rings are twisted strongly relative to the plane of the amide group. The dihedral angle between the two benzene rings ranges from 70.6 (2) to 74.2 (2)°. The N—H bond is anti to the meta-methyl substituent in the aniline fragment in three of the four symmetry-independent mol­ecules. In the fourth mol­ecule, the aniline unit is disordered over two nearly coplanar positions; the anti and syn conformers occupy the same site in the crystal with equal probability. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959694/ /pubmed/21581101 http://dx.doi.org/10.1107/S1600536808035186 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
N-(3-Methyl­phen­yl)benzamide
title N-(3-Methyl­phen­yl)benzamide
title_full N-(3-Methyl­phen­yl)benzamide
title_fullStr N-(3-Methyl­phen­yl)benzamide
title_full_unstemmed N-(3-Methyl­phen­yl)benzamide
title_short N-(3-Methyl­phen­yl)benzamide
title_sort n-(3-methyl­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959694/
https://www.ncbi.nlm.nih.gov/pubmed/21581101
http://dx.doi.org/10.1107/S1600536808035186
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