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Bis(ethyl 2-amino-4-thia­zoleacetato-κN)silver(I) nitrate

In the title complex, [Ag(C(7)H(10)N(2)O(2)S)(2)]NO(3), the Ag(I) cation is bicoordinated in an almost linear configuration by two N-donor atoms of the thia­zole rings of two distinct ethyl 2-amino-4-thia­zoleacetate (EATA) ligands. The dihedral angle between the two thia­zole rings is 49.9°. A weak...

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Detalles Bibliográficos
Autores principales: Zhang, Lai-Jun, Shen, Xing-Can, Liang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959695/
https://www.ncbi.nlm.nih.gov/pubmed/21580862
http://dx.doi.org/10.1107/S1600536808032686
Descripción
Sumario:In the title complex, [Ag(C(7)H(10)N(2)O(2)S)(2)]NO(3), the Ag(I) cation is bicoordinated in an almost linear configuration by two N-donor atoms of the thia­zole rings of two distinct ethyl 2-amino-4-thia­zoleacetate (EATA) ligands. The dihedral angle between the two thia­zole rings is 49.9°. A weak Ag⋯O (2.729 Å) inter­action between the Ag cation and one of the O atoms from the nitrate anion is observed, and a pseudo-dimer is formed through a weak Ag⋯S (3.490 Å) inter­action between the Ag cation and the S atom of the thia­zole ring of a symmetry-related mol­ecule. In the crystal structure, there are intra- and inter­molecular N—H⋯O hydrogen bonds. The occurrence of inter­molecular N—H⋯O hydrogen bonds results in the formation of two-dimensional sheets parallel to (010), which are further linked into a three-dimensional network through weak C—H⋯O inter­actions.