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Bis(ethyl 2-amino-4-thiazoleacetato-κN)silver(I) nitrate
In the title complex, [Ag(C(7)H(10)N(2)O(2)S)(2)]NO(3), the Ag(I) cation is bicoordinated in an almost linear configuration by two N-donor atoms of the thiazole rings of two distinct ethyl 2-amino-4-thiazoleacetate (EATA) ligands. The dihedral angle between the two thiazole rings is 49.9°. A weak...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959695/ https://www.ncbi.nlm.nih.gov/pubmed/21580862 http://dx.doi.org/10.1107/S1600536808032686 |
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author | Zhang, Lai-Jun Shen, Xing-Can Liang, Hong |
author_facet | Zhang, Lai-Jun Shen, Xing-Can Liang, Hong |
author_sort | Zhang, Lai-Jun |
collection | PubMed |
description | In the title complex, [Ag(C(7)H(10)N(2)O(2)S)(2)]NO(3), the Ag(I) cation is bicoordinated in an almost linear configuration by two N-donor atoms of the thiazole rings of two distinct ethyl 2-amino-4-thiazoleacetate (EATA) ligands. The dihedral angle between the two thiazole rings is 49.9°. A weak Ag⋯O (2.729 Å) interaction between the Ag cation and one of the O atoms from the nitrate anion is observed, and a pseudo-dimer is formed through a weak Ag⋯S (3.490 Å) interaction between the Ag cation and the S atom of the thiazole ring of a symmetry-related molecule. In the crystal structure, there are intra- and intermolecular N—H⋯O hydrogen bonds. The occurrence of intermolecular N—H⋯O hydrogen bonds results in the formation of two-dimensional sheets parallel to (010), which are further linked into a three-dimensional network through weak C—H⋯O interactions. |
format | Text |
id | pubmed-2959695 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29596952010-12-30 Bis(ethyl 2-amino-4-thiazoleacetato-κN)silver(I) nitrate Zhang, Lai-Jun Shen, Xing-Can Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Ag(C(7)H(10)N(2)O(2)S)(2)]NO(3), the Ag(I) cation is bicoordinated in an almost linear configuration by two N-donor atoms of the thiazole rings of two distinct ethyl 2-amino-4-thiazoleacetate (EATA) ligands. The dihedral angle between the two thiazole rings is 49.9°. A weak Ag⋯O (2.729 Å) interaction between the Ag cation and one of the O atoms from the nitrate anion is observed, and a pseudo-dimer is formed through a weak Ag⋯S (3.490 Å) interaction between the Ag cation and the S atom of the thiazole ring of a symmetry-related molecule. In the crystal structure, there are intra- and intermolecular N—H⋯O hydrogen bonds. The occurrence of intermolecular N—H⋯O hydrogen bonds results in the formation of two-dimensional sheets parallel to (010), which are further linked into a three-dimensional network through weak C—H⋯O interactions. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959695/ /pubmed/21580862 http://dx.doi.org/10.1107/S1600536808032686 Text en © Zhang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhang, Lai-Jun Shen, Xing-Can Liang, Hong Bis(ethyl 2-amino-4-thiazoleacetato-κN)silver(I) nitrate |
title | Bis(ethyl 2-amino-4-thiazoleacetato-κN)silver(I) nitrate |
title_full | Bis(ethyl 2-amino-4-thiazoleacetato-κN)silver(I) nitrate |
title_fullStr | Bis(ethyl 2-amino-4-thiazoleacetato-κN)silver(I) nitrate |
title_full_unstemmed | Bis(ethyl 2-amino-4-thiazoleacetato-κN)silver(I) nitrate |
title_short | Bis(ethyl 2-amino-4-thiazoleacetato-κN)silver(I) nitrate |
title_sort | bis(ethyl 2-amino-4-thiazoleacetato-κn)silver(i) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959695/ https://www.ncbi.nlm.nih.gov/pubmed/21580862 http://dx.doi.org/10.1107/S1600536808032686 |
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