Cargando…
1-(4-Bromophenyl)ferrocene
In the title compound, [Fe(C(5)H(5))(C(11)H(8)Br)], the distance of the Fe atom from the centroids of the unsubstituted and substituted cyclopentadienyl (Cp) rings is 1.644 (1) and 1.643 (1) Å, respectively. The ferrocenyl moiety deviates from an eclipsed geometry, with marginally tilted Cp rings...
| Autores principales: | , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959700/ https://www.ncbi.nlm.nih.gov/pubmed/21580832 http://dx.doi.org/10.1107/S1600536808031759 |
| _version_ | 1782188562413780992 |
|---|---|
| author | Nyamori, Vincent O. Bala, Muhammad D. |
| author_facet | Nyamori, Vincent O. Bala, Muhammad D. |
| author_sort | Nyamori, Vincent O. |
| collection | PubMed |
| description | In the title compound, [Fe(C(5)H(5))(C(11)H(8)Br)], the distance of the Fe atom from the centroids of the unsubstituted and substituted cyclopentadienyl (Cp) rings is 1.644 (1) and 1.643 (1) Å, respectively. The ferrocenyl moiety deviates from an eclipsed geometry, with marginally tilted Cp rings and an interplanar angle between the Cp and benzene rings of 13.0 (4)°. The crystal structure is stabilized by C—H⋯π interactions between a cyclopentadienyl H atom and the cyclopentadienyl ring of a neighbouring molecule. |
| format | Text |
| id | pubmed-2959700 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29597002010-12-30 1-(4-Bromophenyl)ferrocene Nyamori, Vincent O. Bala, Muhammad D. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Fe(C(5)H(5))(C(11)H(8)Br)], the distance of the Fe atom from the centroids of the unsubstituted and substituted cyclopentadienyl (Cp) rings is 1.644 (1) and 1.643 (1) Å, respectively. The ferrocenyl moiety deviates from an eclipsed geometry, with marginally tilted Cp rings and an interplanar angle between the Cp and benzene rings of 13.0 (4)°. The crystal structure is stabilized by C—H⋯π interactions between a cyclopentadienyl H atom and the cyclopentadienyl ring of a neighbouring molecule. International Union of Crystallography 2008-10-09 /pmc/articles/PMC2959700/ /pubmed/21580832 http://dx.doi.org/10.1107/S1600536808031759 Text en © Nyamori and Bala 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Nyamori, Vincent O. Bala, Muhammad D. 1-(4-Bromophenyl)ferrocene |
| title | 1-(4-Bromophenyl)ferrocene |
| title_full | 1-(4-Bromophenyl)ferrocene |
| title_fullStr | 1-(4-Bromophenyl)ferrocene |
| title_full_unstemmed | 1-(4-Bromophenyl)ferrocene |
| title_short | 1-(4-Bromophenyl)ferrocene |
| title_sort | 1-(4-bromophenyl)ferrocene |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959700/ https://www.ncbi.nlm.nih.gov/pubmed/21580832 http://dx.doi.org/10.1107/S1600536808031759 |
| work_keys_str_mv | AT nyamorivincento 14bromophenylferrocene AT balamuhammadd 14bromophenylferrocene |