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(m-Phenyl­enedimethyl­ene)diammonium dichloride

The asymmetric unit of the title compound, C(8)H(14)N(2) (2+)·2Cl(−), contains one and a half of the dications and three chloride anions. The half molecule is completed by crystallographic twofold symmetry with two C atoms lying on the rotation axis. The two ammonium groups in each cation adopt a tr...

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Detalles Bibliográficos
Autores principales: Cheng, Hua, Li, Huisheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959707/
https://www.ncbi.nlm.nih.gov/pubmed/21580926
http://dx.doi.org/10.1107/S1600536808031334
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author Cheng, Hua
Li, Huisheng
author_facet Cheng, Hua
Li, Huisheng
author_sort Cheng, Hua
collection PubMed
description The asymmetric unit of the title compound, C(8)H(14)N(2) (2+)·2Cl(−), contains one and a half of the dications and three chloride anions. The half molecule is completed by crystallographic twofold symmetry with two C atoms lying on the rotation axis. The two ammonium groups in each cation adopt a trans conformation with respect ot the benzene ring. The ammonium groups and chloride anions are involved in the formation of a three-dimensional N—H⋯Cl hydrogen-bonding network, which stabilizes the crystal packing.
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spelling pubmed-29597072010-12-30 (m-Phenyl­enedimethyl­ene)diammonium dichloride Cheng, Hua Li, Huisheng Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(8)H(14)N(2) (2+)·2Cl(−), contains one and a half of the dications and three chloride anions. The half molecule is completed by crystallographic twofold symmetry with two C atoms lying on the rotation axis. The two ammonium groups in each cation adopt a trans conformation with respect ot the benzene ring. The ammonium groups and chloride anions are involved in the formation of a three-dimensional N—H⋯Cl hydrogen-bonding network, which stabilizes the crystal packing. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959707/ /pubmed/21580926 http://dx.doi.org/10.1107/S1600536808031334 Text en © Cheng and Li 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Cheng, Hua
Li, Huisheng
(m-Phenyl­enedimethyl­ene)diammonium dichloride
title (m-Phenyl­enedimethyl­ene)diammonium dichloride
title_full (m-Phenyl­enedimethyl­ene)diammonium dichloride
title_fullStr (m-Phenyl­enedimethyl­ene)diammonium dichloride
title_full_unstemmed (m-Phenyl­enedimethyl­ene)diammonium dichloride
title_short (m-Phenyl­enedimethyl­ene)diammonium dichloride
title_sort (m-phenyl­enedimethyl­ene)diammonium dichloride
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959707/
https://www.ncbi.nlm.nih.gov/pubmed/21580926
http://dx.doi.org/10.1107/S1600536808031334
work_keys_str_mv AT chenghua mphenylenedimethylenediammoniumdichloride
AT lihuisheng mphenylenedimethylenediammoniumdichloride