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Bis(4-amino­benzoato-κO)triphenylanti­mony(V)

The structure of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], contains two independent mol­ecules of similar configuration. The Sb atoms exhibit a distorted trigonal–bipyramidal geometry with the O atoms of two carboxyl­ate groups in the axial positions and the C atoms of the phenyl grou...

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Detalles Bibliográficos
Autores principales: Wen, Liyuan, Yin, Handong, Wang, Daqi, Cui, Liansheng, Yang, Minglei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959708/
https://www.ncbi.nlm.nih.gov/pubmed/21580870
http://dx.doi.org/10.1107/S1600536808032844
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author Wen, Liyuan
Yin, Handong
Wang, Daqi
Cui, Liansheng
Yang, Minglei
author_facet Wen, Liyuan
Yin, Handong
Wang, Daqi
Cui, Liansheng
Yang, Minglei
author_sort Wen, Liyuan
collection PubMed
description The structure of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], contains two independent mol­ecules of similar configuration. The Sb atoms exhibit a distorted trigonal–bipyramidal geometry with the O atoms of two carboxyl­ate groups in the axial positions and the C atoms of the phenyl groups in the equatorial positions. In the crystal structure, mol­ecules are connected by inter­molecular N—H⋯O and N—H⋯N hydrogen-bonding inter­actions forming a chain structure along [100].
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spelling pubmed-29597082010-12-30 Bis(4-amino­benzoato-κO)triphenylanti­mony(V) Wen, Liyuan Yin, Handong Wang, Daqi Cui, Liansheng Yang, Minglei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Sb(C(6)H(5))(3)(C(7)H(6)NO(2))(2)], contains two independent mol­ecules of similar configuration. The Sb atoms exhibit a distorted trigonal–bipyramidal geometry with the O atoms of two carboxyl­ate groups in the axial positions and the C atoms of the phenyl groups in the equatorial positions. In the crystal structure, mol­ecules are connected by inter­molecular N—H⋯O and N—H⋯N hydrogen-bonding inter­actions forming a chain structure along [100]. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959708/ /pubmed/21580870 http://dx.doi.org/10.1107/S1600536808032844 Text en © Wen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wen, Liyuan
Yin, Handong
Wang, Daqi
Cui, Liansheng
Yang, Minglei
Bis(4-amino­benzoato-κO)triphenylanti­mony(V)
title Bis(4-amino­benzoato-κO)triphenylanti­mony(V)
title_full Bis(4-amino­benzoato-κO)triphenylanti­mony(V)
title_fullStr Bis(4-amino­benzoato-κO)triphenylanti­mony(V)
title_full_unstemmed Bis(4-amino­benzoato-κO)triphenylanti­mony(V)
title_short Bis(4-amino­benzoato-κO)triphenylanti­mony(V)
title_sort bis(4-amino­benzoato-κo)triphenylanti­mony(v)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959708/
https://www.ncbi.nlm.nih.gov/pubmed/21580870
http://dx.doi.org/10.1107/S1600536808032844
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