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[N-(5-Bromo-2-oxidobenzyl­idene)-l-valin­ato-κ(3) O,N,O′]diethyl­tin(IV)

The Sn atom of the title compound, [Sn(C(2)H(5))(2)(C(12)H(12)BrNO(3))], is in a distorted SnNC(2)O(2) trigonal–bipyramidal geometry and forms five- and six-membered chelate rings with the tridentate ligand. One C atom of one ethyl group is disordered with site occupancies of 0.61 (3):0.39 (3)....

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Detalles Bibliográficos
Autores principales: Wang, Wei, Tian, Laijin, Chen, Dengtai, Qu, Yuan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959713/
https://www.ncbi.nlm.nih.gov/pubmed/21580854
http://dx.doi.org/10.1107/S1600536808032388
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author Wang, Wei
Tian, Laijin
Chen, Dengtai
Qu, Yuan
author_facet Wang, Wei
Tian, Laijin
Chen, Dengtai
Qu, Yuan
author_sort Wang, Wei
collection PubMed
description The Sn atom of the title compound, [Sn(C(2)H(5))(2)(C(12)H(12)BrNO(3))], is in a distorted SnNC(2)O(2) trigonal–bipyramidal geometry and forms five- and six-membered chelate rings with the tridentate ligand. One C atom of one ethyl group is disordered with site occupancies of 0.61 (3):0.39 (3).
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spelling pubmed-29597132010-12-30 [N-(5-Bromo-2-oxidobenzyl­idene)-l-valin­ato-κ(3) O,N,O′]diethyl­tin(IV) Wang, Wei Tian, Laijin Chen, Dengtai Qu, Yuan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Sn atom of the title compound, [Sn(C(2)H(5))(2)(C(12)H(12)BrNO(3))], is in a distorted SnNC(2)O(2) trigonal–bipyramidal geometry and forms five- and six-membered chelate rings with the tridentate ligand. One C atom of one ethyl group is disordered with site occupancies of 0.61 (3):0.39 (3). International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959713/ /pubmed/21580854 http://dx.doi.org/10.1107/S1600536808032388 Text en © Wang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Wei
Tian, Laijin
Chen, Dengtai
Qu, Yuan
[N-(5-Bromo-2-oxidobenzyl­idene)-l-valin­ato-κ(3) O,N,O′]diethyl­tin(IV)
title [N-(5-Bromo-2-oxidobenzyl­idene)-l-valin­ato-κ(3) O,N,O′]diethyl­tin(IV)
title_full [N-(5-Bromo-2-oxidobenzyl­idene)-l-valin­ato-κ(3) O,N,O′]diethyl­tin(IV)
title_fullStr [N-(5-Bromo-2-oxidobenzyl­idene)-l-valin­ato-κ(3) O,N,O′]diethyl­tin(IV)
title_full_unstemmed [N-(5-Bromo-2-oxidobenzyl­idene)-l-valin­ato-κ(3) O,N,O′]diethyl­tin(IV)
title_short [N-(5-Bromo-2-oxidobenzyl­idene)-l-valin­ato-κ(3) O,N,O′]diethyl­tin(IV)
title_sort [n-(5-bromo-2-oxidobenzyl­idene)-l-valin­ato-κ(3) o,n,o′]diethyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959713/
https://www.ncbi.nlm.nih.gov/pubmed/21580854
http://dx.doi.org/10.1107/S1600536808032388
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