(E)-Ethyl N′-(3,4,5-trimethoxy­benzyl­idene)hydrazinecarboxyl­ate

The mol­ecule of the title compound, C(13)H(18)N(2)O(5), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxylic acid plane is 49.75 (5)° and an intra­molecular C—H⋯O inter­action occurs. In the crystal structure, the mol­ecu...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Ding, Xiao-Ming, Yu, Wen-Bo, Li, Wei-Wei, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959716/
https://www.ncbi.nlm.nih.gov/pubmed/21580989
http://dx.doi.org/10.1107/S1600536808033461
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author Lv, Lu-Ping
Ding, Xiao-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Ding, Xiao-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description The mol­ecule of the title compound, C(13)H(18)N(2)O(5), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxylic acid plane is 49.75 (5)° and an intra­molecular C—H⋯O inter­action occurs. In the crystal structure, the mol­ecules are linked into a chain along [010] by N—H⋯O hydrogen bonds, and a C—H⋯π contact further stabilizes the structure.
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spelling pubmed-29597162010-12-30 (E)-Ethyl N′-(3,4,5-trimethoxy­benzyl­idene)hydrazinecarboxyl­ate Lv, Lu-Ping Ding, Xiao-Ming Yu, Wen-Bo Li, Wei-Wei Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(13)H(18)N(2)O(5), adopts a trans configuration with respect to the C=N bond. The dihedral angle between the benzene ring and the hydrazinecarboxylic acid plane is 49.75 (5)° and an intra­molecular C—H⋯O inter­action occurs. In the crystal structure, the mol­ecules are linked into a chain along [010] by N—H⋯O hydrogen bonds, and a C—H⋯π contact further stabilizes the structure. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959716/ /pubmed/21580989 http://dx.doi.org/10.1107/S1600536808033461 Text en © Lv et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Ding, Xiao-Ming
Yu, Wen-Bo
Li, Wei-Wei
Hu, Xian-Chao
(E)-Ethyl N′-(3,4,5-trimethoxy­benzyl­idene)hydrazinecarboxyl­ate
title (E)-Ethyl N′-(3,4,5-trimethoxy­benzyl­idene)hydrazinecarboxyl­ate
title_full (E)-Ethyl N′-(3,4,5-trimethoxy­benzyl­idene)hydrazinecarboxyl­ate
title_fullStr (E)-Ethyl N′-(3,4,5-trimethoxy­benzyl­idene)hydrazinecarboxyl­ate
title_full_unstemmed (E)-Ethyl N′-(3,4,5-trimethoxy­benzyl­idene)hydrazinecarboxyl­ate
title_short (E)-Ethyl N′-(3,4,5-trimethoxy­benzyl­idene)hydrazinecarboxyl­ate
title_sort (e)-ethyl n′-(3,4,5-trimethoxy­benzyl­idene)hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959716/
https://www.ncbi.nlm.nih.gov/pubmed/21580989
http://dx.doi.org/10.1107/S1600536808033461
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