[Bis(diphenyl­phosphino)methane-κ(2) P,P′][bis­(diphenyl­phosphinometh­yl)diethoxy­silane-κ(2) P,P′]bis­(dinitro­gen)­molybdenum(0) benzene 0.7-solvate

In the crystal structure of the title compound, [Mo(C(25)H(22)P(2))(C(30)H(34)O(2)P(2)Si)(N(2))(2)]·0.7C(6)H(6), the Mo atoms are coordinated by four P atoms and two N atoms in a distorted octa­hedral mode. The two C atoms of one of the two eth­oxy groups are disordered and were refined using a spli...

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Detalles Bibliográficos
Autores principales: Klatt, Kristina, Näther, Christian, Tuczek, Felix
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959717/
https://www.ncbi.nlm.nih.gov/pubmed/21580836
http://dx.doi.org/10.1107/S1600536808032364
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author Klatt, Kristina
Näther, Christian
Tuczek, Felix
author_facet Klatt, Kristina
Näther, Christian
Tuczek, Felix
author_sort Klatt, Kristina
collection PubMed
description In the crystal structure of the title compound, [Mo(C(25)H(22)P(2))(C(30)H(34)O(2)P(2)Si)(N(2))(2)]·0.7C(6)H(6), the Mo atoms are coordinated by four P atoms and two N atoms in a distorted octa­hedral mode. The two C atoms of one of the two eth­oxy groups are disordered and were refined using a split model and site-occupation factors of 0.7:0.3. The crystal structure contains a benzene solvent mol­ecule with a site occupation of 70%.
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spelling pubmed-29597172010-12-30 [Bis(diphenyl­phosphino)methane-κ(2) P,P′][bis­(diphenyl­phosphinometh­yl)diethoxy­silane-κ(2) P,P′]bis­(dinitro­gen)­molybdenum(0) benzene 0.7-solvate Klatt, Kristina Näther, Christian Tuczek, Felix Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound, [Mo(C(25)H(22)P(2))(C(30)H(34)O(2)P(2)Si)(N(2))(2)]·0.7C(6)H(6), the Mo atoms are coordinated by four P atoms and two N atoms in a distorted octa­hedral mode. The two C atoms of one of the two eth­oxy groups are disordered and were refined using a split model and site-occupation factors of 0.7:0.3. The crystal structure contains a benzene solvent mol­ecule with a site occupation of 70%. International Union of Crystallography 2008-10-11 /pmc/articles/PMC2959717/ /pubmed/21580836 http://dx.doi.org/10.1107/S1600536808032364 Text en © Klatt et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Klatt, Kristina
Näther, Christian
Tuczek, Felix
[Bis(diphenyl­phosphino)methane-κ(2) P,P′][bis­(diphenyl­phosphinometh­yl)diethoxy­silane-κ(2) P,P′]bis­(dinitro­gen)­molybdenum(0) benzene 0.7-solvate
title [Bis(diphenyl­phosphino)methane-κ(2) P,P′][bis­(diphenyl­phosphinometh­yl)diethoxy­silane-κ(2) P,P′]bis­(dinitro­gen)­molybdenum(0) benzene 0.7-solvate
title_full [Bis(diphenyl­phosphino)methane-κ(2) P,P′][bis­(diphenyl­phosphinometh­yl)diethoxy­silane-κ(2) P,P′]bis­(dinitro­gen)­molybdenum(0) benzene 0.7-solvate
title_fullStr [Bis(diphenyl­phosphino)methane-κ(2) P,P′][bis­(diphenyl­phosphinometh­yl)diethoxy­silane-κ(2) P,P′]bis­(dinitro­gen)­molybdenum(0) benzene 0.7-solvate
title_full_unstemmed [Bis(diphenyl­phosphino)methane-κ(2) P,P′][bis­(diphenyl­phosphinometh­yl)diethoxy­silane-κ(2) P,P′]bis­(dinitro­gen)­molybdenum(0) benzene 0.7-solvate
title_short [Bis(diphenyl­phosphino)methane-κ(2) P,P′][bis­(diphenyl­phosphinometh­yl)diethoxy­silane-κ(2) P,P′]bis­(dinitro­gen)­molybdenum(0) benzene 0.7-solvate
title_sort [bis(diphenyl­phosphino)methane-κ(2) p,p′][bis­(diphenyl­phosphinometh­yl)diethoxy­silane-κ(2) p,p′]bis­(dinitro­gen)­molybdenum(0) benzene 0.7-solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959717/
https://www.ncbi.nlm.nih.gov/pubmed/21580836
http://dx.doi.org/10.1107/S1600536808032364
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AT natherchristian bisdiphenylphosphinomethanek2ppbisdiphenylphosphinomethyldiethoxysilanek2ppbisdinitrogenmolybdenum0benzene07solvate
AT tuczekfelix bisdiphenylphosphinomethanek2ppbisdiphenylphosphinomethyldiethoxysilanek2ppbisdinitrogenmolybdenum0benzene07solvate

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