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Bis[1,2-bis(dimethylphosphino)ethane-κ(2) P,P′]rhodium(I) dichlorido[(1,2,5,6-η)-1,5-cyclooctadiene]rhodium(I)
In the title complex, [Rh(C(6)H(16)P(2))(2)][RhCl(2)(C(8)H(12))], the asymmetric unit contains two [Rh(dmpe)(2)] [dmpe = 1,2-bis(dimethylphosphino)ethane] half-cations, lying on inversion centers, and an [RhCl(2)(cod)](−) (cod = 1,5-cyclooctadiene) anion, wherein Rh is coordinated by two chlorid...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959718/ https://www.ncbi.nlm.nih.gov/pubmed/21580855 http://dx.doi.org/10.1107/S1600536808032509 |
| Sumario: | In the title complex, [Rh(C(6)H(16)P(2))(2)][RhCl(2)(C(8)H(12))], the asymmetric unit contains two [Rh(dmpe)(2)] [dmpe = 1,2-bis(dimethylphosphino)ethane] half-cations, lying on inversion centers, and an [RhCl(2)(cod)](−) (cod = 1,5-cyclooctadiene) anion, wherein Rh is coordinated by two chloride ligands and two olefinic π-bonds of the cyclooctadiene ligand. The Rh atoms in the cations and anion exhibit square-planar coordination and are separated without any unusual interactions. |
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