Hexaamminecobalt(III) hexa­cyanido­manganate(III)

The asymmetric unit of the title compound, [Co(NH(3))(6)][Mn(CN)(6)], contains one Co and one Mn atom, both lying on threefold inversion axes, and one NH(3) and one CN group. The octa­hedral environments around Co(II) and Mn(II) are generated by symmetry and show very slight deviations from ideal ge...

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Detalles Bibliográficos
Autores principales: Visser, Hendrik G., Purcell, Walter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959719/
https://www.ncbi.nlm.nih.gov/pubmed/21580812
http://dx.doi.org/10.1107/S1600536808032881
Descripción
Sumario:The asymmetric unit of the title compound, [Co(NH(3))(6)][Mn(CN)(6)], contains one Co and one Mn atom, both lying on threefold inversion axes, and one NH(3) and one CN group. The octa­hedral environments around Co(II) and Mn(II) are generated by symmetry and show very slight deviations from ideal geometry. A three-dimensional network is created by N—H⋯N hydrogen bonds.

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