Hexaamminecobalt(III) hexa­cyanido­manganate(III)

The asymmetric unit of the title compound, [Co(NH(3))(6)][Mn(CN)(6)], contains one Co and one Mn atom, both lying on threefold inversion axes, and one NH(3) and one CN group. The octa­hedral environments around Co(II) and Mn(II) are generated by symmetry and show very slight deviations from ideal ge...

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Detalles Bibliográficos
Autores principales: Visser, Hendrik G., Purcell, Walter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959719/
https://www.ncbi.nlm.nih.gov/pubmed/21580812
http://dx.doi.org/10.1107/S1600536808032881
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author Visser, Hendrik G.
Purcell, Walter
author_facet Visser, Hendrik G.
Purcell, Walter
author_sort Visser, Hendrik G.
collection PubMed
description The asymmetric unit of the title compound, [Co(NH(3))(6)][Mn(CN)(6)], contains one Co and one Mn atom, both lying on threefold inversion axes, and one NH(3) and one CN group. The octa­hedral environments around Co(II) and Mn(II) are generated by symmetry and show very slight deviations from ideal geometry. A three-dimensional network is created by N—H⋯N hydrogen bonds.
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spelling pubmed-29597192010-12-30 Hexaamminecobalt(III) hexa­cyanido­manganate(III) Visser, Hendrik G. Purcell, Walter Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The asymmetric unit of the title compound, [Co(NH(3))(6)][Mn(CN)(6)], contains one Co and one Mn atom, both lying on threefold inversion axes, and one NH(3) and one CN group. The octa­hedral environments around Co(II) and Mn(II) are generated by symmetry and show very slight deviations from ideal geometry. A three-dimensional network is created by N—H⋯N hydrogen bonds. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959719/ /pubmed/21580812 http://dx.doi.org/10.1107/S1600536808032881 Text en © Visser and Purcell 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Visser, Hendrik G.
Purcell, Walter
Hexaamminecobalt(III) hexa­cyanido­manganate(III)
title Hexaamminecobalt(III) hexa­cyanido­manganate(III)
title_full Hexaamminecobalt(III) hexa­cyanido­manganate(III)
title_fullStr Hexaamminecobalt(III) hexa­cyanido­manganate(III)
title_full_unstemmed Hexaamminecobalt(III) hexa­cyanido­manganate(III)
title_short Hexaamminecobalt(III) hexa­cyanido­manganate(III)
title_sort hexaamminecobalt(iii) hexa­cyanido­manganate(iii)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959719/
https://www.ncbi.nlm.nih.gov/pubmed/21580812
http://dx.doi.org/10.1107/S1600536808032881
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