Bis(2-amino­pyridine-κN (1))silver(I) nitrate

The asymmetric unit of the title compound, [Ag(C(5)H(6)N(2))(2)]NO(3), consists of one and a half each of both cations and anions, the other halves being generated by crystallographic inversion centres. One of the Ag(I) atoms lies on an inversion center and one of the nitrate ions is disordered acro...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, John, Jain, Jebas, Samuel Robinson, Balasubramanian, T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959721/
https://www.ncbi.nlm.nih.gov/pubmed/21580820
http://dx.doi.org/10.1107/S1600536808031292
Descripción
Sumario:The asymmetric unit of the title compound, [Ag(C(5)H(6)N(2))(2)]NO(3), consists of one and a half each of both cations and anions, the other halves being generated by crystallographic inversion centres. One of the Ag(I) atoms lies on an inversion center and one of the nitrate ions is disordered across an inversion center. Each Ag(I) atom is bicoordinated in a linear geometry by two N atoms from two 2-amino­pyridine ligands. In the crystal structure, the cations and anions are linked into a two-dimensional network parallel to (001) by N—H⋯O and C—H⋯O hydrogen bonds.

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