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Bis(2-aminopyridine-κN (1))silver(I) nitrate
The asymmetric unit of the title compound, [Ag(C(5)H(6)N(2))(2)]NO(3), consists of one and a half each of both cations and anions, the other halves being generated by crystallographic inversion centres. One of the Ag(I) atoms lies on an inversion center and one of the nitrate ions is disordered acro...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959721/ https://www.ncbi.nlm.nih.gov/pubmed/21580820 http://dx.doi.org/10.1107/S1600536808031292 |
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author | Fun, Hoong-Kun John, Jain Jebas, Samuel Robinson Balasubramanian, T. |
author_facet | Fun, Hoong-Kun John, Jain Jebas, Samuel Robinson Balasubramanian, T. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The asymmetric unit of the title compound, [Ag(C(5)H(6)N(2))(2)]NO(3), consists of one and a half each of both cations and anions, the other halves being generated by crystallographic inversion centres. One of the Ag(I) atoms lies on an inversion center and one of the nitrate ions is disordered across an inversion center. Each Ag(I) atom is bicoordinated in a linear geometry by two N atoms from two 2-aminopyridine ligands. In the crystal structure, the cations and anions are linked into a two-dimensional network parallel to (001) by N—H⋯O and C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2959721 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29597212010-12-30 Bis(2-aminopyridine-κN (1))silver(I) nitrate Fun, Hoong-Kun John, Jain Jebas, Samuel Robinson Balasubramanian, T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ag(C(5)H(6)N(2))(2)]NO(3), consists of one and a half each of both cations and anions, the other halves being generated by crystallographic inversion centres. One of the Ag(I) atoms lies on an inversion center and one of the nitrate ions is disordered across an inversion center. Each Ag(I) atom is bicoordinated in a linear geometry by two N atoms from two 2-aminopyridine ligands. In the crystal structure, the cations and anions are linked into a two-dimensional network parallel to (001) by N—H⋯O and C—H⋯O hydrogen bonds. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959721/ /pubmed/21580820 http://dx.doi.org/10.1107/S1600536808031292 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Fun, Hoong-Kun John, Jain Jebas, Samuel Robinson Balasubramanian, T. Bis(2-aminopyridine-κN (1))silver(I) nitrate |
title | Bis(2-aminopyridine-κN
(1))silver(I) nitrate |
title_full | Bis(2-aminopyridine-κN
(1))silver(I) nitrate |
title_fullStr | Bis(2-aminopyridine-κN
(1))silver(I) nitrate |
title_full_unstemmed | Bis(2-aminopyridine-κN
(1))silver(I) nitrate |
title_short | Bis(2-aminopyridine-κN
(1))silver(I) nitrate |
title_sort | bis(2-aminopyridine-κn
(1))silver(i) nitrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959721/ https://www.ncbi.nlm.nih.gov/pubmed/21580820 http://dx.doi.org/10.1107/S1600536808031292 |
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