Triphen­yl(tetra­hydro­furan)­aluminium(III)

In the title compound, [Al(C(6)H(5))(3)(C(4)H(8)O)], the Al atom has a distorted tetra­hedral geometry. The C—Al—C angles range from 113.25 (7) to 116.27 (8)°, much larger than the O—Al—C angles, which range from 103.39 (7) to 103.90 (6)°. The tetra­hydro­furan ring adopts an envelope conformation....

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Detalles Bibliográficos
Autores principales: Chen, Chi-Ren, Gau, Han-Mou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959725/
https://www.ncbi.nlm.nih.gov/pubmed/21580835
http://dx.doi.org/10.1107/S1600536808032091
Descripción
Sumario:In the title compound, [Al(C(6)H(5))(3)(C(4)H(8)O)], the Al atom has a distorted tetra­hedral geometry. The C—Al—C angles range from 113.25 (7) to 116.27 (8)°, much larger than the O—Al—C angles, which range from 103.39 (7) to 103.90 (6)°. The tetra­hydro­furan ring adopts an envelope conformation. The crystal packing is stabilized by C—H⋯π inter­actions.

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