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Triphenyl(tetrahydrofuran)aluminium(III)
In the title compound, [Al(C(6)H(5))(3)(C(4)H(8)O)], the Al atom has a distorted tetrahedral geometry. The C—Al—C angles range from 113.25 (7) to 116.27 (8)°, much larger than the O—Al—C angles, which range from 103.39 (7) to 103.90 (6)°. The tetrahydrofuran ring adopts an envelope conformation....
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959725/ https://www.ncbi.nlm.nih.gov/pubmed/21580835 http://dx.doi.org/10.1107/S1600536808032091 |
| _version_ | 1782188568341381120 |
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| author | Chen, Chi-Ren Gau, Han-Mou |
| author_facet | Chen, Chi-Ren Gau, Han-Mou |
| author_sort | Chen, Chi-Ren |
| collection | PubMed |
| description | In the title compound, [Al(C(6)H(5))(3)(C(4)H(8)O)], the Al atom has a distorted tetrahedral geometry. The C—Al—C angles range from 113.25 (7) to 116.27 (8)°, much larger than the O—Al—C angles, which range from 103.39 (7) to 103.90 (6)°. The tetrahydrofuran ring adopts an envelope conformation. The crystal packing is stabilized by C—H⋯π interactions. |
| format | Text |
| id | pubmed-2959725 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29597252010-12-30 Triphenyl(tetrahydrofuran)aluminium(III) Chen, Chi-Ren Gau, Han-Mou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Al(C(6)H(5))(3)(C(4)H(8)O)], the Al atom has a distorted tetrahedral geometry. The C—Al—C angles range from 113.25 (7) to 116.27 (8)°, much larger than the O—Al—C angles, which range from 103.39 (7) to 103.90 (6)°. The tetrahydrofuran ring adopts an envelope conformation. The crystal packing is stabilized by C—H⋯π interactions. International Union of Crystallography 2008-10-11 /pmc/articles/PMC2959725/ /pubmed/21580835 http://dx.doi.org/10.1107/S1600536808032091 Text en © Chen and Gau 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Chi-Ren Gau, Han-Mou Triphenyl(tetrahydrofuran)aluminium(III) |
| title | Triphenyl(tetrahydrofuran)aluminium(III) |
| title_full | Triphenyl(tetrahydrofuran)aluminium(III) |
| title_fullStr | Triphenyl(tetrahydrofuran)aluminium(III) |
| title_full_unstemmed | Triphenyl(tetrahydrofuran)aluminium(III) |
| title_short | Triphenyl(tetrahydrofuran)aluminium(III) |
| title_sort | triphenyl(tetrahydrofuran)aluminium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959725/ https://www.ncbi.nlm.nih.gov/pubmed/21580835 http://dx.doi.org/10.1107/S1600536808032091 |
| work_keys_str_mv | AT chenchiren triphenyltetrahydrofuranaluminiumiii AT gauhanmou triphenyltetrahydrofuranaluminiumiii |