Aqua­(2,2′-bipyrid­yl)(pyrazine-2,6-dicarboxyl­ato)nickel(II) 1.25-hydrate

The asymmetric unit of the title compound, [Ni(C(6)H(2)N(2)O(4))(C(10)H(8)N(2))(H(2)O)]·1.25H(2)O, contains two independent chemically identical Ni(II) complex cations and two and a half solvent water mol­ecules. The Ni(II) ions are in slightly distorted coordination environments. In the crystal str...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Feng-Qin, Zhang, Yuan-Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959726/
https://www.ncbi.nlm.nih.gov/pubmed/21580913
http://dx.doi.org/10.1107/S1600536808034806
_version_ 1782188568588845056
author Wang, Feng-Qin
Zhang, Yuan-Fang
author_facet Wang, Feng-Qin
Zhang, Yuan-Fang
author_sort Wang, Feng-Qin
collection PubMed
description The asymmetric unit of the title compound, [Ni(C(6)H(2)N(2)O(4))(C(10)H(8)N(2))(H(2)O)]·1.25H(2)O, contains two independent chemically identical Ni(II) complex cations and two and a half solvent water mol­ecules. The Ni(II) ions are in slightly distorted coordination environments. In the crystal structure, inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds link cations and water mol­ecules into a three-dimensional network. One of the three uncoordinated water molecules is half-occupied.
format Text
id pubmed-2959726
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29597262010-12-30 Aqua­(2,2′-bipyrid­yl)(pyrazine-2,6-dicarboxyl­ato)nickel(II) 1.25-hydrate Wang, Feng-Qin Zhang, Yuan-Fang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(6)H(2)N(2)O(4))(C(10)H(8)N(2))(H(2)O)]·1.25H(2)O, contains two independent chemically identical Ni(II) complex cations and two and a half solvent water mol­ecules. The Ni(II) ions are in slightly distorted coordination environments. In the crystal structure, inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds link cations and water mol­ecules into a three-dimensional network. One of the three uncoordinated water molecules is half-occupied. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959726/ /pubmed/21580913 http://dx.doi.org/10.1107/S1600536808034806 Text en © Feng-Qin and Yuan-Fang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Feng-Qin
Zhang, Yuan-Fang
Aqua­(2,2′-bipyrid­yl)(pyrazine-2,6-dicarboxyl­ato)nickel(II) 1.25-hydrate
title Aqua­(2,2′-bipyrid­yl)(pyrazine-2,6-dicarboxyl­ato)nickel(II) 1.25-hydrate
title_full Aqua­(2,2′-bipyrid­yl)(pyrazine-2,6-dicarboxyl­ato)nickel(II) 1.25-hydrate
title_fullStr Aqua­(2,2′-bipyrid­yl)(pyrazine-2,6-dicarboxyl­ato)nickel(II) 1.25-hydrate
title_full_unstemmed Aqua­(2,2′-bipyrid­yl)(pyrazine-2,6-dicarboxyl­ato)nickel(II) 1.25-hydrate
title_short Aqua­(2,2′-bipyrid­yl)(pyrazine-2,6-dicarboxyl­ato)nickel(II) 1.25-hydrate
title_sort aqua­(2,2′-bipyrid­yl)(pyrazine-2,6-dicarboxyl­ato)nickel(ii) 1.25-hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959726/
https://www.ncbi.nlm.nih.gov/pubmed/21580913
http://dx.doi.org/10.1107/S1600536808034806
work_keys_str_mv AT wangfengqin aqua22bipyridylpyrazine26dicarboxylatonickelii125hydrate
AT zhangyuanfang aqua22bipyridylpyrazine26dicarboxylatonickelii125hydrate

Ejemplares similares