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Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cadmium(II) dihydrate

The title complex, [Cd(Paba)(2)]·2H(2)O or [Cd(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, was synthesized by the reaction of the potassium salt of 2-(2-pyridylmethyl­eneamino)benzene­sulfonic acid (PabaK) with CdCl(2)·2.5H(2)O in methanol. The Cd(II) atom lies on a crystallographic twofold axis and is coordina...

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Detalles Bibliográficos
Autores principales: Ou-Yang, Miao, Huang, Xue-Ren, Zhang, Yun-Liang, Jiang, Yi-Min
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959732/
https://www.ncbi.nlm.nih.gov/pubmed/21580899
http://dx.doi.org/10.1107/S1600536808034387
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author Ou-Yang, Miao
Huang, Xue-Ren
Zhang, Yun-Liang
Jiang, Yi-Min
author_facet Ou-Yang, Miao
Huang, Xue-Ren
Zhang, Yun-Liang
Jiang, Yi-Min
author_sort Ou-Yang, Miao
collection PubMed
description The title complex, [Cd(Paba)(2)]·2H(2)O or [Cd(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, was synthesized by the reaction of the potassium salt of 2-(2-pyridylmethyl­eneamino)benzene­sulfonic acid (PabaK) with CdCl(2)·2.5H(2)O in methanol. The Cd(II) atom lies on a crystallographic twofold axis and is coordinated by four N atoms and two O atoms from two deprotonated tridentate 2-(2-pyridylmethyl­eneamino)benzene­sulfonate ligands in a slightly distorted octa­hedral environment. There are extensive hydrogen bonds of the type O—H⋯O between the uncoordinated water molecules and the sulfonate O atoms, through which the complex forms a layered structure parallel to (001).
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spelling pubmed-29597322010-12-30 Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cadmium(II) dihydrate Ou-Yang, Miao Huang, Xue-Ren Zhang, Yun-Liang Jiang, Yi-Min Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(Paba)(2)]·2H(2)O or [Cd(C(12)H(9)N(2)O(3)S)(2)]·2H(2)O, was synthesized by the reaction of the potassium salt of 2-(2-pyridylmethyl­eneamino)benzene­sulfonic acid (PabaK) with CdCl(2)·2.5H(2)O in methanol. The Cd(II) atom lies on a crystallographic twofold axis and is coordinated by four N atoms and two O atoms from two deprotonated tridentate 2-(2-pyridylmethyl­eneamino)benzene­sulfonate ligands in a slightly distorted octa­hedral environment. There are extensive hydrogen bonds of the type O—H⋯O between the uncoordinated water molecules and the sulfonate O atoms, through which the complex forms a layered structure parallel to (001). International Union of Crystallography 2008-10-25 /pmc/articles/PMC2959732/ /pubmed/21580899 http://dx.doi.org/10.1107/S1600536808034387 Text en © Ou-Yang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ou-Yang, Miao
Huang, Xue-Ren
Zhang, Yun-Liang
Jiang, Yi-Min
Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cadmium(II) dihydrate
title Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cadmium(II) dihydrate
title_full Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cadmium(II) dihydrate
title_fullStr Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cadmium(II) dihydrate
title_full_unstemmed Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cadmium(II) dihydrate
title_short Bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) N,N′,O]cadmium(II) dihydrate
title_sort bis[2-(2-pyridylmethyl­eneamino)benzene­sulfonato-κ(3) n,n′,o]cadmium(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959732/
https://www.ncbi.nlm.nih.gov/pubmed/21580899
http://dx.doi.org/10.1107/S1600536808034387
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