Isopropyl 2-(4,6-dimethyl-3-methyl­sulfinyl-1-benzofuran-2-yl)acetate

Mol­ecules of title compound, C(16)H(20)O(4)S, which was synthesized by the oxidation of isopropyl 2-(4,6-dimethyl-3-methyl­sulfanyl-1-benzofuran-2-yl)acetate, inter­act through C—H⋯π inter­actions between a methyl­ene H atom and the aromatic carbon ring of the benzofuran ring system, and by C—H⋯O h...

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Detalles Bibliográficos
Autores principales: Choi, Hong Dae, Seo, Pil Ja, Son, Byeng Wha, Lee, Uk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959738/
https://www.ncbi.nlm.nih.gov/pubmed/21581061
http://dx.doi.org/10.1107/S1600536808034466
Descripción
Sumario:Mol­ecules of title compound, C(16)H(20)O(4)S, which was synthesized by the oxidation of isopropyl 2-(4,6-dimethyl-3-methyl­sulfanyl-1-benzofuran-2-yl)acetate, inter­act through C—H⋯π inter­actions between a methyl­ene H atom and the aromatic carbon ring of the benzofuran ring system, and by C—H⋯O hydrogen bonds. Adjacent stacked mol­ecules exhibit a carbon­yl–carbonyl inter­action [3.295 (2) Å]. The O atom of the methyl­sulfinyl group is disordered over two positions with site-occupancy factors of 0.9 and 0.1.

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