(E)-2-Chloro-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide

In the structue of the title compound, C(18)H(13)ClN(2)O(2), a new Schiff base, the dihedral angle between the benzene and naphthyl ring system mean planes is 22.5 (2)°. The mol­ecule has an E configuration about the C=N bond, and an intra­molecular hydrogen bond involving the hydoxyl substituent on...

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Detalles Bibliográficos
Autores principales: Qiu, Feng, Zhao, Li-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959739/
https://www.ncbi.nlm.nih.gov/pubmed/21580933
http://dx.doi.org/10.1107/S1600536808031371
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author Qiu, Feng
Zhao, Li-Mei
author_facet Qiu, Feng
Zhao, Li-Mei
author_sort Qiu, Feng
collection PubMed
description In the structue of the title compound, C(18)H(13)ClN(2)O(2), a new Schiff base, the dihedral angle between the benzene and naphthyl ring system mean planes is 22.5 (2)°. The mol­ecule has an E configuration about the C=N bond, and an intra­molecular hydrogen bond involving the hydoxyl substituent on the naphthyl ring and the N′ atom of the hydrazide. The crystal structure is stabilized by inter­molecular N—H⋯O hydrogen bonds, forming one-dimensional chains running parallel to the a axis.
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spelling pubmed-29597392010-12-30 (E)-2-Chloro-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide Qiu, Feng Zhao, Li-Mei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structue of the title compound, C(18)H(13)ClN(2)O(2), a new Schiff base, the dihedral angle between the benzene and naphthyl ring system mean planes is 22.5 (2)°. The mol­ecule has an E configuration about the C=N bond, and an intra­molecular hydrogen bond involving the hydoxyl substituent on the naphthyl ring and the N′ atom of the hydrazide. The crystal structure is stabilized by inter­molecular N—H⋯O hydrogen bonds, forming one-dimensional chains running parallel to the a axis. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959739/ /pubmed/21580933 http://dx.doi.org/10.1107/S1600536808031371 Text en © Qiu and Zhao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Qiu, Feng
Zhao, Li-Mei
(E)-2-Chloro-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title (E)-2-Chloro-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_full (E)-2-Chloro-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_fullStr (E)-2-Chloro-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_full_unstemmed (E)-2-Chloro-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_short (E)-2-Chloro-N′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
title_sort (e)-2-chloro-n′-(2-hydr­oxy-1-naphthyl­methyl­ene)benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959739/
https://www.ncbi.nlm.nih.gov/pubmed/21580933
http://dx.doi.org/10.1107/S1600536808031371
work_keys_str_mv AT qiufeng e2chloron2hydroxy1naphthylmethylenebenzohydrazide
AT zhaolimei e2chloron2hydroxy1naphthylmethylenebenzohydrazide

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