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5-Bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one

In the title 1,3,2-dioxaphospho­rinane derivative, C(10)H(11)Br(2)O(4)P, the 1,3,2-dioxaphospho­rinane ring adopts a chair conformation, having the P=O bond equatorially oriented and the phen­oxy group axially oriented. The bromo substituent is in an axial position opposite to the phen­oxy group and...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Adak, Avijit Kr., Maity, Annada C., Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959742/
https://www.ncbi.nlm.nih.gov/pubmed/21581083
http://dx.doi.org/10.1107/S1600536808033631
Descripción
Sumario:In the title 1,3,2-dioxaphospho­rinane derivative, C(10)H(11)Br(2)O(4)P, the 1,3,2-dioxaphospho­rinane ring adopts a chair conformation, having the P=O bond equatorially oriented and the phen­oxy group axially oriented. The bromo substituent is in an axial position opposite to the phen­oxy group and the bromo­methyl group is in an equatorial position opposite to the P=O bond. In the crystal packing, mol­ecules are linked through weak C—H⋯O and C—H⋯Br inter­actions to form chains along the b axis. The chains are arranged into sheets parallel to the ab plane. In adjacent sheets, mol­ecules are arranged in an anti­parallel fashion. Inter­molecular C—H⋯π inter­actions are also observed.