5-Bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one

In the title 1,3,2-dioxaphospho­rinane derivative, C(10)H(11)Br(2)O(4)P, the 1,3,2-dioxaphospho­rinane ring adopts a chair conformation, having the P=O bond equatorially oriented and the phen­oxy group axially oriented. The bromo substituent is in an axial position opposite to the phen­oxy group and...

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Autores principales: Fun, Hoong-Kun, Chantrapromma, Suchada, Adak, Avijit Kr., Maity, Annada C., Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959742/
https://www.ncbi.nlm.nih.gov/pubmed/21581083
http://dx.doi.org/10.1107/S1600536808033631
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author Fun, Hoong-Kun
Chantrapromma, Suchada
Adak, Avijit Kr.
Maity, Annada C.
Goswami, Shyamaprosad
author_facet Fun, Hoong-Kun
Chantrapromma, Suchada
Adak, Avijit Kr.
Maity, Annada C.
Goswami, Shyamaprosad
author_sort Fun, Hoong-Kun
collection PubMed
description In the title 1,3,2-dioxaphospho­rinane derivative, C(10)H(11)Br(2)O(4)P, the 1,3,2-dioxaphospho­rinane ring adopts a chair conformation, having the P=O bond equatorially oriented and the phen­oxy group axially oriented. The bromo substituent is in an axial position opposite to the phen­oxy group and the bromo­methyl group is in an equatorial position opposite to the P=O bond. In the crystal packing, mol­ecules are linked through weak C—H⋯O and C—H⋯Br inter­actions to form chains along the b axis. The chains are arranged into sheets parallel to the ab plane. In adjacent sheets, mol­ecules are arranged in an anti­parallel fashion. Inter­molecular C—H⋯π inter­actions are also observed.
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spelling pubmed-29597422010-12-30 5-Bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one Fun, Hoong-Kun Chantrapromma, Suchada Adak, Avijit Kr. Maity, Annada C. Goswami, Shyamaprosad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title 1,3,2-dioxaphospho­rinane derivative, C(10)H(11)Br(2)O(4)P, the 1,3,2-dioxaphospho­rinane ring adopts a chair conformation, having the P=O bond equatorially oriented and the phen­oxy group axially oriented. The bromo substituent is in an axial position opposite to the phen­oxy group and the bromo­methyl group is in an equatorial position opposite to the P=O bond. In the crystal packing, mol­ecules are linked through weak C—H⋯O and C—H⋯Br inter­actions to form chains along the b axis. The chains are arranged into sheets parallel to the ab plane. In adjacent sheets, mol­ecules are arranged in an anti­parallel fashion. Inter­molecular C—H⋯π inter­actions are also observed. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959742/ /pubmed/21581083 http://dx.doi.org/10.1107/S1600536808033631 Text en © Fun et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chantrapromma, Suchada
Adak, Avijit Kr.
Maity, Annada C.
Goswami, Shyamaprosad
5-Bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one
title 5-Bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one
title_full 5-Bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one
title_fullStr 5-Bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one
title_full_unstemmed 5-Bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one
title_short 5-Bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one
title_sort 5-bromo-5-bromo­methyl-2-phen­oxy-1,3,2-dioxaphospho­rinan-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959742/
https://www.ncbi.nlm.nih.gov/pubmed/21581083
http://dx.doi.org/10.1107/S1600536808033631
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