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catena-Poly[[[bis[aquanickel(II)]bis(μ-pyridine-2,6-dicarboxylato N-oxide)]-μ-1,2-di-4-pyridylethane] tetrahydrate]
In the title compound, {[Ni(2)(C(7)H(3)NO(5))(2)(C(12)H(12)N(2))(H(2)O)(2)]·4H(2)O}(n), two Ni(II) ions, two tridentate pyridine-2,6-dicarboxylate N-oxide ligands and two coordinated water molecules form centrosymmetric dinuclear units, which are further bridged by centrosymmetric 1,2-di-4-pyridyl...
Autor principal: | |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959744/ https://www.ncbi.nlm.nih.gov/pubmed/21580819 http://dx.doi.org/10.1107/S1600536808031619 |
Sumario: | In the title compound, {[Ni(2)(C(7)H(3)NO(5))(2)(C(12)H(12)N(2))(H(2)O)(2)]·4H(2)O}(n), two Ni(II) ions, two tridentate pyridine-2,6-dicarboxylate N-oxide ligands and two coordinated water molecules form centrosymmetric dinuclear units, which are further bridged by centrosymmetric 1,2-di-4-pyridylethane ligands into polymeric chains along [210]. Each Ni(II) ion has a distorted square-pyramidal environment, with the basal plane formed by three O [Ni—O = 1.9290 (16)–1.9588 (10) Å] and one N [Ni—N = 1.9828 (18) Å] atoms and the apical position occupied by the water molecule [Ni—O = 2.2643 (11) Å]. The water molecules are involved in the formation of O—H⋯O hydrogen bonds. |
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