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catena-Poly[[[bis­[aqua­nickel(II)]bis­(μ-pyridine-2,6-dicarboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]

In the title compound, {[Ni(2)(C(7)H(3)NO(5))(2)(C(12)H(12)N(2))(H(2)O)(2)]·4H(2)O}(n), two Ni(II) ions, two tridentate pyridine-2,6-dicarboxyl­ate N-oxide ligands and two coordinated water mol­ecules form centrosymmetric dinuclear units, which are further bridged by centrosymmetric 1,2-di-4-pyridyl...

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Detalles Bibliográficos
Autor principal: Yang, Ming-Hua
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959744/
https://www.ncbi.nlm.nih.gov/pubmed/21580819
http://dx.doi.org/10.1107/S1600536808031619
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author Yang, Ming-Hua
author_facet Yang, Ming-Hua
author_sort Yang, Ming-Hua
collection PubMed
description In the title compound, {[Ni(2)(C(7)H(3)NO(5))(2)(C(12)H(12)N(2))(H(2)O)(2)]·4H(2)O}(n), two Ni(II) ions, two tridentate pyridine-2,6-dicarboxyl­ate N-oxide ligands and two coordinated water mol­ecules form centrosymmetric dinuclear units, which are further bridged by centrosymmetric 1,2-di-4-pyridylethane ligands into polymeric chains along [210]. Each Ni(II) ion has a distorted square-pyramidal environment, with the basal plane formed by three O [Ni—O = 1.9290 (16)–1.9588 (10) Å] and one N [Ni—N = 1.9828 (18) Å] atoms and the apical position occupied by the water mol­ecule [Ni—O = 2.2643 (11) Å]. The water mol­ecules are involved in the formation of O—H⋯O hydrogen bonds.
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spelling pubmed-29597442010-12-30 catena-Poly[[[bis­[aqua­nickel(II)]bis­(μ-pyridine-2,6-dicarboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate] Yang, Ming-Hua Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Ni(2)(C(7)H(3)NO(5))(2)(C(12)H(12)N(2))(H(2)O)(2)]·4H(2)O}(n), two Ni(II) ions, two tridentate pyridine-2,6-dicarboxyl­ate N-oxide ligands and two coordinated water mol­ecules form centrosymmetric dinuclear units, which are further bridged by centrosymmetric 1,2-di-4-pyridylethane ligands into polymeric chains along [210]. Each Ni(II) ion has a distorted square-pyramidal environment, with the basal plane formed by three O [Ni—O = 1.9290 (16)–1.9588 (10) Å] and one N [Ni—N = 1.9828 (18) Å] atoms and the apical position occupied by the water mol­ecule [Ni—O = 2.2643 (11) Å]. The water mol­ecules are involved in the formation of O—H⋯O hydrogen bonds. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959744/ /pubmed/21580819 http://dx.doi.org/10.1107/S1600536808031619 Text en © Ming-Hua Yang 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Ming-Hua
catena-Poly[[[bis­[aqua­nickel(II)]bis­(μ-pyridine-2,6-dicarboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]
title catena-Poly[[[bis­[aqua­nickel(II)]bis­(μ-pyridine-2,6-dicarboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]
title_full catena-Poly[[[bis­[aqua­nickel(II)]bis­(μ-pyridine-2,6-dicarboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]
title_fullStr catena-Poly[[[bis­[aqua­nickel(II)]bis­(μ-pyridine-2,6-dicarboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]
title_full_unstemmed catena-Poly[[[bis­[aqua­nickel(II)]bis­(μ-pyridine-2,6-dicarboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]
title_short catena-Poly[[[bis­[aqua­nickel(II)]bis­(μ-pyridine-2,6-dicarboxyl­ato N-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]
title_sort catena-poly[[[bis­[aqua­nickel(ii)]bis­(μ-pyridine-2,6-dicarboxyl­ato n-oxide)]-μ-1,2-di-4-pyridylethane] tetra­hydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959744/
https://www.ncbi.nlm.nih.gov/pubmed/21580819
http://dx.doi.org/10.1107/S1600536808031619
work_keys_str_mv AT yangminghua catenapolybisaquanickeliibismpyridine26dicarboxylatonoxidem12di4pyridylethanetetrahydrate