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5,5-Bis(4-methoxy­phen­yl)-2,8-bis­[3-(trifluoro­meth­yl)phen­yl]-5H-cyclo­penta­[2,1-b:3,4-b’]dipyridine

The title compound, C(39)H(26)F(6)N(2)O(2), showed two melting transitions 477.4 and 506.5 K in a differential scanning calorimetry (DSC) study. The first of these can be attributed to a melting phase transition arising from the rotation of two trifluoro­methyl groups. In the crystal structure, both...

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Detalles Bibliográficos
Autores principales: Ono, Katsuhiko, Tomura, Masaaki, Saito, Katsuhiro
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959745/
https://www.ncbi.nlm.nih.gov/pubmed/21581042
http://dx.doi.org/10.1107/S160053680803420X
Descripción
Sumario:The title compound, C(39)H(26)F(6)N(2)O(2), showed two melting transitions 477.4 and 506.5 K in a differential scanning calorimetry (DSC) study. The first of these can be attributed to a melting phase transition arising from the rotation of two trifluoro­methyl groups. In the crystal structure, both trifluoro­methyl groups are disordered over two sites with occupancy factors of 0.660 (17) and 0.340 (17) for the major and minor orientations, respectively. The introduction of trifluoro­methyl groups inhibits π-stacking between the diaza­fluorene (cyclo­penta­[2,1-b:3,4-b’]dipyridine) units. Three short F⋯O contacts between 2.80 (3) and 2.95 (1) Å are observed in the crystal structure.