catena-Poly[[(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))nickel(II)]-μ-terephthalato-κ(2) O (1):O (4)]

In the title compound, [Ni(C(8)H(4)O(4))(C(36)H(44)N(4)O(4))](n), the Ni(II) atom is coordinated in a distorted octa­hedral geometry by the four N atoms of the 1,12,15,26-tetra­aza-5,8,19,22-tetra-oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane ligand and two O atoms from the terephthalate dia...

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Detalles Bibliográficos
Autores principales: Meng, Shuang-Ming, Fan, Yue-Qin, Guo, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959746/
https://www.ncbi.nlm.nih.gov/pubmed/21580874
http://dx.doi.org/10.1107/S160053680803314X
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author Meng, Shuang-Ming
Fan, Yue-Qin
Guo, Yong
author_facet Meng, Shuang-Ming
Fan, Yue-Qin
Guo, Yong
author_sort Meng, Shuang-Ming
collection PubMed
description In the title compound, [Ni(C(8)H(4)O(4))(C(36)H(44)N(4)O(4))](n), the Ni(II) atom is coordinated in a distorted octa­hedral geometry by the four N atoms of the 1,12,15,26-tetra­aza-5,8,19,22-tetra-oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane ligand and two O atoms from the terephthalate dianions. The Ni(II) atoms, which lie on inversion centres, are linked via terephthalate ligands to form a chain structure along [101]. The structure is stabilized by three intra­molecular and one inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-29597462010-12-30 catena-Poly[[(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))nickel(II)]-μ-terephthalato-κ(2) O (1):O (4)] Meng, Shuang-Ming Fan, Yue-Qin Guo, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(8)H(4)O(4))(C(36)H(44)N(4)O(4))](n), the Ni(II) atom is coordinated in a distorted octa­hedral geometry by the four N atoms of the 1,12,15,26-tetra­aza-5,8,19,22-tetra-oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane ligand and two O atoms from the terephthalate dianions. The Ni(II) atoms, which lie on inversion centres, are linked via terephthalate ligands to form a chain structure along [101]. The structure is stabilized by three intra­molecular and one inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959746/ /pubmed/21580874 http://dx.doi.org/10.1107/S160053680803314X Text en © Meng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Shuang-Ming
Fan, Yue-Qin
Guo, Yong
catena-Poly[[(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))nickel(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title catena-Poly[[(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))nickel(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_full catena-Poly[[(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))nickel(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_fullStr catena-Poly[[(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))nickel(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_full_unstemmed catena-Poly[[(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))nickel(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_short catena-Poly[[(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))nickel(II)]-μ-terephthalato-κ(2) O (1):O (4)]
title_sort catena-poly[[(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) n (1),n (12),n (15),n (26))nickel(ii)]-μ-terephthalato-κ(2) o (1):o (4)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959746/
https://www.ncbi.nlm.nih.gov/pubmed/21580874
http://dx.doi.org/10.1107/S160053680803314X
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