(η(5)-Cyclo­penta­dien­yl)[η(6)-diethyl eth­yl(phen­yl)malonate]iron(II) hexa­fluorido­phosphate

At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(15)H(20)O(4))]PF(6), are almost parallel [dihedral angle between planes = 4.10 (14)°]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the...

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Detalles Bibliográficos
Autores principales: Jenkins, Hilary A., Masuda, Jason D., Piórko, Adam
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959750/
https://www.ncbi.nlm.nih.gov/pubmed/21580821
http://dx.doi.org/10.1107/S1600536808030523
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author Jenkins, Hilary A.
Masuda, Jason D.
Piórko, Adam
author_facet Jenkins, Hilary A.
Masuda, Jason D.
Piórko, Adam
author_sort Jenkins, Hilary A.
collection PubMed
description At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(15)H(20)O(4))]PF(6), are almost parallel [dihedral angle between planes = 4.10 (14)°]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom. The F atoms of the PF(6) (−) anion were found to be equally disordered over two sites.
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spelling pubmed-29597502010-12-30 (η(5)-Cyclo­penta­dien­yl)[η(6)-diethyl eth­yl(phen­yl)malonate]iron(II) hexa­fluorido­phosphate Jenkins, Hilary A. Masuda, Jason D. Piórko, Adam Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers At 223 (2) K, the complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(15)H(20)O(4))]PF(6), are almost parallel [dihedral angle between planes = 4.10 (14)°]. Among the C atoms of the complexed arene ring, the quaternary C atom is located at the longest distance from the Fe atom. The F atoms of the PF(6) (−) anion were found to be equally disordered over two sites. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959750/ /pubmed/21580821 http://dx.doi.org/10.1107/S1600536808030523 Text en © Jenkins et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jenkins, Hilary A.
Masuda, Jason D.
Piórko, Adam
(η(5)-Cyclo­penta­dien­yl)[η(6)-diethyl eth­yl(phen­yl)malonate]iron(II) hexa­fluorido­phosphate
title (η(5)-Cyclo­penta­dien­yl)[η(6)-diethyl eth­yl(phen­yl)malonate]iron(II) hexa­fluorido­phosphate
title_full (η(5)-Cyclo­penta­dien­yl)[η(6)-diethyl eth­yl(phen­yl)malonate]iron(II) hexa­fluorido­phosphate
title_fullStr (η(5)-Cyclo­penta­dien­yl)[η(6)-diethyl eth­yl(phen­yl)malonate]iron(II) hexa­fluorido­phosphate
title_full_unstemmed (η(5)-Cyclo­penta­dien­yl)[η(6)-diethyl eth­yl(phen­yl)malonate]iron(II) hexa­fluorido­phosphate
title_short (η(5)-Cyclo­penta­dien­yl)[η(6)-diethyl eth­yl(phen­yl)malonate]iron(II) hexa­fluorido­phosphate
title_sort (η(5)-cyclo­penta­dien­yl)[η(6)-diethyl eth­yl(phen­yl)malonate]iron(ii) hexa­fluorido­phosphate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959750/
https://www.ncbi.nlm.nih.gov/pubmed/21580821
http://dx.doi.org/10.1107/S1600536808030523
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