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Bis(μ-2-hydroxy­benozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis­[(2-hydroxy­benozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]

The dinuclear title compound, [Cd(2)(C(7)H(5)O(3))(4)(C(12)H(8)N(2))(2)], is located on a crystallographic rotation twofold axis. The two Cd(II) ions are connected by two tridentate bridging 2-hydroxy­benzoate anions. Each Cd(II) ion is seven-coordinated by five O atoms from three 2-hydroxy­benzoate...

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Detalles Bibliográficos
Autores principales: Shi, Qing-Yuan, Li, Zhi-Cheng, Cheng, Zong-Sheng, Tan, Jing-Bo, Liu, Jia-Lun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959752/
https://www.ncbi.nlm.nih.gov/pubmed/21580896
http://dx.doi.org/10.1107/S1600536808033886
Descripción
Sumario:The dinuclear title compound, [Cd(2)(C(7)H(5)O(3))(4)(C(12)H(8)N(2))(2)], is located on a crystallographic rotation twofold axis. The two Cd(II) ions are connected by two tridentate bridging 2-hydroxy­benzoate anions. Each Cd(II) ion is seven-coordinated by five O atoms from three 2-hydroxy­benzoate ligands and two N atoms from 1,10-phenanthroline. The 2-hydroxy­benzoate mol­ecules adopt two kinds of coordination mode, bidentate chelating and tridentate bridging–chelating. Intra­molecular hydrogen bonds between hydr­oxy and carboxyl­ate groups from 2-hydroxy­benzoate groups and π–π stacking interactions between parallel 1,10-phenanthroline ligands [centroid–centroid distances = 3.707 (3) and 3.842 (3) Å] are observed. Furthermore, adjacent benzene rings from 2-hydroxy­benzoate ligands are involved in π–π inter­actions with inter­planar distances of 3.642 (3) Å, thereby forming a chain along the a axis direction.