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Bis(μ-2-hydroxy­benozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis­[(2-hydroxy­benozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]

The dinuclear title compound, [Cd(2)(C(7)H(5)O(3))(4)(C(12)H(8)N(2))(2)], is located on a crystallographic rotation twofold axis. The two Cd(II) ions are connected by two tridentate bridging 2-hydroxy­benzoate anions. Each Cd(II) ion is seven-coordinated by five O atoms from three 2-hydroxy­benzoate...

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Autores principales: Shi, Qing-Yuan, Li, Zhi-Cheng, Cheng, Zong-Sheng, Tan, Jing-Bo, Liu, Jia-Lun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959752/
https://www.ncbi.nlm.nih.gov/pubmed/21580896
http://dx.doi.org/10.1107/S1600536808033886
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author Shi, Qing-Yuan
Li, Zhi-Cheng
Cheng, Zong-Sheng
Tan, Jing-Bo
Liu, Jia-Lun
author_facet Shi, Qing-Yuan
Li, Zhi-Cheng
Cheng, Zong-Sheng
Tan, Jing-Bo
Liu, Jia-Lun
author_sort Shi, Qing-Yuan
collection PubMed
description The dinuclear title compound, [Cd(2)(C(7)H(5)O(3))(4)(C(12)H(8)N(2))(2)], is located on a crystallographic rotation twofold axis. The two Cd(II) ions are connected by two tridentate bridging 2-hydroxy­benzoate anions. Each Cd(II) ion is seven-coordinated by five O atoms from three 2-hydroxy­benzoate ligands and two N atoms from 1,10-phenanthroline. The 2-hydroxy­benzoate mol­ecules adopt two kinds of coordination mode, bidentate chelating and tridentate bridging–chelating. Intra­molecular hydrogen bonds between hydr­oxy and carboxyl­ate groups from 2-hydroxy­benzoate groups and π–π stacking interactions between parallel 1,10-phenanthroline ligands [centroid–centroid distances = 3.707 (3) and 3.842 (3) Å] are observed. Furthermore, adjacent benzene rings from 2-hydroxy­benzoate ligands are involved in π–π inter­actions with inter­planar distances of 3.642 (3) Å, thereby forming a chain along the a axis direction.
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spelling pubmed-29597522010-12-30 Bis(μ-2-hydroxy­benozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis­[(2-hydroxy­benozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)] Shi, Qing-Yuan Li, Zhi-Cheng Cheng, Zong-Sheng Tan, Jing-Bo Liu, Jia-Lun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Cd(2)(C(7)H(5)O(3))(4)(C(12)H(8)N(2))(2)], is located on a crystallographic rotation twofold axis. The two Cd(II) ions are connected by two tridentate bridging 2-hydroxy­benzoate anions. Each Cd(II) ion is seven-coordinated by five O atoms from three 2-hydroxy­benzoate ligands and two N atoms from 1,10-phenanthroline. The 2-hydroxy­benzoate mol­ecules adopt two kinds of coordination mode, bidentate chelating and tridentate bridging–chelating. Intra­molecular hydrogen bonds between hydr­oxy and carboxyl­ate groups from 2-hydroxy­benzoate groups and π–π stacking interactions between parallel 1,10-phenanthroline ligands [centroid–centroid distances = 3.707 (3) and 3.842 (3) Å] are observed. Furthermore, adjacent benzene rings from 2-hydroxy­benzoate ligands are involved in π–π inter­actions with inter­planar distances of 3.642 (3) Å, thereby forming a chain along the a axis direction. International Union of Crystallography 2008-10-25 /pmc/articles/PMC2959752/ /pubmed/21580896 http://dx.doi.org/10.1107/S1600536808033886 Text en © Shi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Qing-Yuan
Li, Zhi-Cheng
Cheng, Zong-Sheng
Tan, Jing-Bo
Liu, Jia-Lun
Bis(μ-2-hydroxy­benozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis­[(2-hydroxy­benozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]
title Bis(μ-2-hydroxy­benozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis­[(2-hydroxy­benozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]
title_full Bis(μ-2-hydroxy­benozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis­[(2-hydroxy­benozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]
title_fullStr Bis(μ-2-hydroxy­benozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis­[(2-hydroxy­benozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]
title_full_unstemmed Bis(μ-2-hydroxy­benozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis­[(2-hydroxy­benozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]
title_short Bis(μ-2-hydroxy­benozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis­[(2-hydroxy­benozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]
title_sort bis(μ-2-hydroxy­benozato)-κ(3) o,o′:o′;κ(3) o:o,o′-bis­[(2-hydroxy­benozato-κ(2) o,o′)(1,10-phenanthroline-κ(2) n,n′)cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959752/
https://www.ncbi.nlm.nih.gov/pubmed/21580896
http://dx.doi.org/10.1107/S1600536808033886
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