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Bis(μ-2-hydroxybenozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis[(2-hydroxybenozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]
The dinuclear title compound, [Cd(2)(C(7)H(5)O(3))(4)(C(12)H(8)N(2))(2)], is located on a crystallographic rotation twofold axis. The two Cd(II) ions are connected by two tridentate bridging 2-hydroxybenzoate anions. Each Cd(II) ion is seven-coordinated by five O atoms from three 2-hydroxybenzoate...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959752/ https://www.ncbi.nlm.nih.gov/pubmed/21580896 http://dx.doi.org/10.1107/S1600536808033886 |
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author | Shi, Qing-Yuan Li, Zhi-Cheng Cheng, Zong-Sheng Tan, Jing-Bo Liu, Jia-Lun |
author_facet | Shi, Qing-Yuan Li, Zhi-Cheng Cheng, Zong-Sheng Tan, Jing-Bo Liu, Jia-Lun |
author_sort | Shi, Qing-Yuan |
collection | PubMed |
description | The dinuclear title compound, [Cd(2)(C(7)H(5)O(3))(4)(C(12)H(8)N(2))(2)], is located on a crystallographic rotation twofold axis. The two Cd(II) ions are connected by two tridentate bridging 2-hydroxybenzoate anions. Each Cd(II) ion is seven-coordinated by five O atoms from three 2-hydroxybenzoate ligands and two N atoms from 1,10-phenanthroline. The 2-hydroxybenzoate molecules adopt two kinds of coordination mode, bidentate chelating and tridentate bridging–chelating. Intramolecular hydrogen bonds between hydroxy and carboxylate groups from 2-hydroxybenzoate groups and π–π stacking interactions between parallel 1,10-phenanthroline ligands [centroid–centroid distances = 3.707 (3) and 3.842 (3) Å] are observed. Furthermore, adjacent benzene rings from 2-hydroxybenzoate ligands are involved in π–π interactions with interplanar distances of 3.642 (3) Å, thereby forming a chain along the a axis direction. |
format | Text |
id | pubmed-2959752 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29597522010-12-30 Bis(μ-2-hydroxybenozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis[(2-hydroxybenozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)] Shi, Qing-Yuan Li, Zhi-Cheng Cheng, Zong-Sheng Tan, Jing-Bo Liu, Jia-Lun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The dinuclear title compound, [Cd(2)(C(7)H(5)O(3))(4)(C(12)H(8)N(2))(2)], is located on a crystallographic rotation twofold axis. The two Cd(II) ions are connected by two tridentate bridging 2-hydroxybenzoate anions. Each Cd(II) ion is seven-coordinated by five O atoms from three 2-hydroxybenzoate ligands and two N atoms from 1,10-phenanthroline. The 2-hydroxybenzoate molecules adopt two kinds of coordination mode, bidentate chelating and tridentate bridging–chelating. Intramolecular hydrogen bonds between hydroxy and carboxylate groups from 2-hydroxybenzoate groups and π–π stacking interactions between parallel 1,10-phenanthroline ligands [centroid–centroid distances = 3.707 (3) and 3.842 (3) Å] are observed. Furthermore, adjacent benzene rings from 2-hydroxybenzoate ligands are involved in π–π interactions with interplanar distances of 3.642 (3) Å, thereby forming a chain along the a axis direction. International Union of Crystallography 2008-10-25 /pmc/articles/PMC2959752/ /pubmed/21580896 http://dx.doi.org/10.1107/S1600536808033886 Text en © Shi et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shi, Qing-Yuan Li, Zhi-Cheng Cheng, Zong-Sheng Tan, Jing-Bo Liu, Jia-Lun Bis(μ-2-hydroxybenozato)-κ(3) O,O′:O′;κ(3) O:O,O′-bis[(2-hydroxybenozato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)] |
title | Bis(μ-2-hydroxybenozato)-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(2-hydroxybenozato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
title_full | Bis(μ-2-hydroxybenozato)-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(2-hydroxybenozato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
title_fullStr | Bis(μ-2-hydroxybenozato)-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(2-hydroxybenozato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
title_full_unstemmed | Bis(μ-2-hydroxybenozato)-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(2-hydroxybenozato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
title_short | Bis(μ-2-hydroxybenozato)-κ(3)
O,O′:O′;κ(3)
O:O,O′-bis[(2-hydroxybenozato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
title_sort | bis(μ-2-hydroxybenozato)-κ(3)
o,o′:o′;κ(3)
o:o,o′-bis[(2-hydroxybenozato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)cadmium(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959752/ https://www.ncbi.nlm.nih.gov/pubmed/21580896 http://dx.doi.org/10.1107/S1600536808033886 |
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