(Benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))cadmium(II) benzene-1,3-dicarboxylic acid solvate

In the title compound, [Cd(C(8)H(4)O(4))(C(36)H(44)N(4)O(4))]·C(8)H(6)O(4), the Cd(II) atom is six-coordinated by four N atoms from the macrocyclic ligand and two O atoms from a benzene-1,3-dicarboxyl­ate ligand. The complex mol­ecules are linked by N—H⋯O hydrogen bonds, forming a one-dimensional ch...

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Detalles Bibliográficos
Autores principales: Jia, Zhi-Fang, Ma, Jian-Fang, Zhang, Lai-Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959761/
https://www.ncbi.nlm.nih.gov/pubmed/21580871
http://dx.doi.org/10.1107/S1600536808033138
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author Jia, Zhi-Fang
Ma, Jian-Fang
Zhang, Lai-Ping
author_facet Jia, Zhi-Fang
Ma, Jian-Fang
Zhang, Lai-Ping
author_sort Jia, Zhi-Fang
collection PubMed
description In the title compound, [Cd(C(8)H(4)O(4))(C(36)H(44)N(4)O(4))]·C(8)H(6)O(4), the Cd(II) atom is six-coordinated by four N atoms from the macrocyclic ligand and two O atoms from a benzene-1,3-dicarboxyl­ate ligand. The complex mol­ecules are linked by N—H⋯O hydrogen bonds, forming a one-dimensional chain structure along the b axis. The chains are further connected through N—H⋯O and O—H⋯O hydrogen bonds between the complex mol­ecule and an uncoordinated benzene-1,3-dicarboxylic acid mol­ecule, resulting in a two-dimensional supra­molecular network.
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spelling pubmed-29597612010-12-30 (Benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))cadmium(II) benzene-1,3-dicarboxylic acid solvate Jia, Zhi-Fang Ma, Jian-Fang Zhang, Lai-Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(8)H(4)O(4))(C(36)H(44)N(4)O(4))]·C(8)H(6)O(4), the Cd(II) atom is six-coordinated by four N atoms from the macrocyclic ligand and two O atoms from a benzene-1,3-dicarboxyl­ate ligand. The complex mol­ecules are linked by N—H⋯O hydrogen bonds, forming a one-dimensional chain structure along the b axis. The chains are further connected through N—H⋯O and O—H⋯O hydrogen bonds between the complex mol­ecule and an uncoordinated benzene-1,3-dicarboxylic acid mol­ecule, resulting in a two-dimensional supra­molecular network. International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959761/ /pubmed/21580871 http://dx.doi.org/10.1107/S1600536808033138 Text en © Jia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jia, Zhi-Fang
Ma, Jian-Fang
Zhang, Lai-Ping
(Benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))cadmium(II) benzene-1,3-dicarboxylic acid solvate
title (Benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))cadmium(II) benzene-1,3-dicarboxylic acid solvate
title_full (Benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))cadmium(II) benzene-1,3-dicarboxylic acid solvate
title_fullStr (Benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))cadmium(II) benzene-1,3-dicarboxylic acid solvate
title_full_unstemmed (Benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))cadmium(II) benzene-1,3-dicarboxylic acid solvate
title_short (Benzene-1,3-dicarboxyl­ato-κ(2) O (1),O (1′))(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) N (1),N (12),N (15),N (26))cadmium(II) benzene-1,3-dicarboxylic acid solvate
title_sort (benzene-1,3-dicarboxyl­ato-κ(2) o (1),o (1′))(1,12,15,26-tetra­aza-5,8,19,22-tetra­oxa-3,4:9,10:17,18:23,24-tetra­benzocyclo­octa­cosane-κ(4) n (1),n (12),n (15),n (26))cadmium(ii) benzene-1,3-dicarboxylic acid solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959761/
https://www.ncbi.nlm.nih.gov/pubmed/21580871
http://dx.doi.org/10.1107/S1600536808033138
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