Tricarbonyl­bis(tricyclo­hexyl­phosphine-κP)ruthenium(0) toluene solvate

The title compound, [Ru(C(18)H(33)P)(2)(CO)(3)]·C(7)H(8), shows a distorted trigonal-bipyramdial coordination around the central Ru atom, with the two phosphine ligands occupying the axial positions. Two toluene mol­ecules per asymmetric unit with site-occupation factors of 0.5 are observed. One of...

Descripción completa

Detalles Bibliográficos
Autores principales: Nader, Andreas, Görls, Helmar, Imhof, Wolfgang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959764/
https://www.ncbi.nlm.nih.gov/pubmed/21580893
http://dx.doi.org/10.1107/S1600536808034211
Descripción
Sumario:The title compound, [Ru(C(18)H(33)P)(2)(CO)(3)]·C(7)H(8), shows a distorted trigonal-bipyramdial coordination around the central Ru atom, with the two phosphine ligands occupying the axial positions. Two toluene mol­ecules per asymmetric unit with site-occupation factors of 0.5 are observed. One of them forces two of the CO ligands to enclose a wider C—Ru—C bond angle [127.5 (3)°] than in the solvent-free crystal structure of [Ru(PCy(3))(2)(CO)(3)] (Cy is cyclo­hexyl).

Ejemplares similares