Tricarbonyl­bis(tricyclo­hexyl­phosphine-κP)ruthenium(0) toluene solvate

The title compound, [Ru(C(18)H(33)P)(2)(CO)(3)]·C(7)H(8), shows a distorted trigonal-bipyramdial coordination around the central Ru atom, with the two phosphine ligands occupying the axial positions. Two toluene mol­ecules per asymmetric unit with site-occupation factors of 0.5 are observed. One of...

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Detalles Bibliográficos
Autores principales: Nader, Andreas, Görls, Helmar, Imhof, Wolfgang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959764/
https://www.ncbi.nlm.nih.gov/pubmed/21580893
http://dx.doi.org/10.1107/S1600536808034211
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author Nader, Andreas
Görls, Helmar
Imhof, Wolfgang
author_facet Nader, Andreas
Görls, Helmar
Imhof, Wolfgang
author_sort Nader, Andreas
collection PubMed
description The title compound, [Ru(C(18)H(33)P)(2)(CO)(3)]·C(7)H(8), shows a distorted trigonal-bipyramdial coordination around the central Ru atom, with the two phosphine ligands occupying the axial positions. Two toluene mol­ecules per asymmetric unit with site-occupation factors of 0.5 are observed. One of them forces two of the CO ligands to enclose a wider C—Ru—C bond angle [127.5 (3)°] than in the solvent-free crystal structure of [Ru(PCy(3))(2)(CO)(3)] (Cy is cyclo­hexyl).
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spelling pubmed-29597642010-12-30 Tricarbonyl­bis(tricyclo­hexyl­phosphine-κP)ruthenium(0) toluene solvate Nader, Andreas Görls, Helmar Imhof, Wolfgang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ru(C(18)H(33)P)(2)(CO)(3)]·C(7)H(8), shows a distorted trigonal-bipyramdial coordination around the central Ru atom, with the two phosphine ligands occupying the axial positions. Two toluene mol­ecules per asymmetric unit with site-occupation factors of 0.5 are observed. One of them forces two of the CO ligands to enclose a wider C—Ru—C bond angle [127.5 (3)°] than in the solvent-free crystal structure of [Ru(PCy(3))(2)(CO)(3)] (Cy is cyclo­hexyl). International Union of Crystallography 2008-10-22 /pmc/articles/PMC2959764/ /pubmed/21580893 http://dx.doi.org/10.1107/S1600536808034211 Text en © Nader et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nader, Andreas
Görls, Helmar
Imhof, Wolfgang
Tricarbonyl­bis(tricyclo­hexyl­phosphine-κP)ruthenium(0) toluene solvate
title Tricarbonyl­bis(tricyclo­hexyl­phosphine-κP)ruthenium(0) toluene solvate
title_full Tricarbonyl­bis(tricyclo­hexyl­phosphine-κP)ruthenium(0) toluene solvate
title_fullStr Tricarbonyl­bis(tricyclo­hexyl­phosphine-κP)ruthenium(0) toluene solvate
title_full_unstemmed Tricarbonyl­bis(tricyclo­hexyl­phosphine-κP)ruthenium(0) toluene solvate
title_short Tricarbonyl­bis(tricyclo­hexyl­phosphine-κP)ruthenium(0) toluene solvate
title_sort tricarbonyl­bis(tricyclo­hexyl­phosphine-κp)ruthenium(0) toluene solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959764/
https://www.ncbi.nlm.nih.gov/pubmed/21580893
http://dx.doi.org/10.1107/S1600536808034211
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AT gorlshelmar tricarbonylbistricyclohexylphosphinekpruthenium0toluenesolvate
AT imhofwolfgang tricarbonylbistricyclohexylphosphinekpruthenium0toluenesolvate

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