Di-μ-acetato-κ(3) O,O′:O;κ(3) O:O,O′-bis­[(acetato-κ(2) O,O′)(1,10-phenan­throline-κ(2) N,N′)cadmium(II)]

The title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(8)N(2))(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordi...

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Detalles Bibliográficos
Autores principales: Harvey, Miguel Angel, Baggio, Sergio, Garland, María Teresa, Baggio, Ricardo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959765/
https://www.ncbi.nlm.nih.gov/pubmed/21580889
http://dx.doi.org/10.1107/S1600536808029462
Descripción
Sumario:The title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(8)N(2))(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single π–π inter­action between stacked phen groups [centroid–centroid distance 3.5209 (11) Å], leading to a planar structure parallel to (010).

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