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Di-μ-acetato-κ(3) O,O′:O;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)]
The title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(8)N(2))(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordi...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959765/ https://www.ncbi.nlm.nih.gov/pubmed/21580889 http://dx.doi.org/10.1107/S1600536808029462 |
| _version_ | 1782188578086846464 |
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| author | Harvey, Miguel Angel Baggio, Sergio Garland, María Teresa Baggio, Ricardo |
| author_facet | Harvey, Miguel Angel Baggio, Sergio Garland, María Teresa Baggio, Ricardo |
| author_sort | Harvey, Miguel Angel |
| collection | PubMed |
| description | The title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(8)N(2))(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single π–π interaction between stacked phen groups [centroid–centroid distance 3.5209 (11) Å], leading to a planar structure parallel to (010). |
| format | Text |
| id | pubmed-2959765 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29597652010-12-30 Di-μ-acetato-κ(3) O,O′:O;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)] Harvey, Miguel Angel Baggio, Sergio Garland, María Teresa Baggio, Ricardo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(2)(C(2)H(3)O(2))(4)(C(12)H(8)N(2))(2)], consists of dimeric units built up around a crystallographic symmetry centre. Each cadmium(II) unit is chelated by a 1,10-phenanthroline (phen) group and two acetate ligands, one of which also acts as a bridge, linking both seven-coordinated cadmium(II) centres. The crystal structure is governed by a single π–π interaction between stacked phen groups [centroid–centroid distance 3.5209 (11) Å], leading to a planar structure parallel to (010). International Union of Crystallography 2008-10-22 /pmc/articles/PMC2959765/ /pubmed/21580889 http://dx.doi.org/10.1107/S1600536808029462 Text en © Harvey et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Harvey, Miguel Angel Baggio, Sergio Garland, María Teresa Baggio, Ricardo Di-μ-acetato-κ(3) O,O′:O;κ(3) O:O,O′-bis[(acetato-κ(2) O,O′)(1,10-phenanthroline-κ(2) N,N′)cadmium(II)] |
| title | Di-μ-acetato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
| title_full | Di-μ-acetato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
| title_fullStr | Di-μ-acetato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
| title_full_unstemmed | Di-μ-acetato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
| title_short | Di-μ-acetato-κ(3)
O,O′:O;κ(3)
O:O,O′-bis[(acetato-κ(2)
O,O′)(1,10-phenanthroline-κ(2)
N,N′)cadmium(II)] |
| title_sort | di-μ-acetato-κ(3)
o,o′:o;κ(3)
o:o,o′-bis[(acetato-κ(2)
o,o′)(1,10-phenanthroline-κ(2)
n,n′)cadmium(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959765/ https://www.ncbi.nlm.nih.gov/pubmed/21580889 http://dx.doi.org/10.1107/S1600536808029462 |
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