Tetra­pyrazine­platinum(II) bis­(tetra­fluoro­borate) acetonitrile hemisolvate

The improved synthesis and characterization of tetra­pyrazine­platinum(II) bis­(tetra­fluoro­borate) acetonitrile hemisolvate, [Pt(C(4)H(4)N(2))(4)](BF(4))(2)·0.5CH(3)CN, is reported. The unit cell contains a half equivalent of an acetonitrile solvent mol­ecule per tetra­pyrazine­platinum(II) ion. T...

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Detalles Bibliográficos
Autores principales: Derry, Paul J., Wang, Xiaoping, Smucker, Bradley W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959766/
https://www.ncbi.nlm.nih.gov/pubmed/21580888
http://dx.doi.org/10.1107/S1600536808033679
Descripción
Sumario:The improved synthesis and characterization of tetra­pyrazine­platinum(II) bis­(tetra­fluoro­borate) acetonitrile hemisolvate, [Pt(C(4)H(4)N(2))(4)](BF(4))(2)·0.5CH(3)CN, is reported. The unit cell contains a half equivalent of an acetonitrile solvent mol­ecule per tetra­pyrazine­platinum(II) ion. The coordination geometry of the Pt(II) ion is almost square-planar, with the Pt atom residing on an inversion center. The BF(4) (−) counter-anion, located at a general position, has an idealized tetra­hedral geometry and an acetonitrile solvent mol­ecule, the methyl group of which is disordered over two equal positions, sits on a twofold rotation axis.

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