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(Acetato-κO)(2-{[2-(dimethylamino)ethylimino](phenyl)methyl}-5-methoxyphenolato-κ(3) N,N′,O (1))copper(II)
The Cu(II) atom in the title complex, [Cu(C(18)H(21)N(2)O(2))(C(2)H(3)O(2))], is tetracoordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar e...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959767/ https://www.ncbi.nlm.nih.gov/pubmed/21580877 http://dx.doi.org/10.1107/S1600536808033114 |
Sumario: | The Cu(II) atom in the title complex, [Cu(C(18)H(21)N(2)O(2))(C(2)H(3)O(2))], is tetracoordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intramolecular interaction toward the Cu atom, the Cu—O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak intermolecular interactions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu—O distance in other crystal structures. |
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