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(Acetato-κO)(2-{[2-(dimethyl­amino)­ethyl­imino](phen­yl)meth­yl}-5-methoxy­phenolato-κ(3) N,N′,O (1))copper(II)

The Cu(II) atom in the title complex, [Cu(C(18)H(21)N(2)O(2))(C(2)H(3)O(2))], is tetra­coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar e...

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Detalles Bibliográficos
Autores principales: Lin, Chieh-Shen, Lin, Chia-Her, Huang, Jui-Hsien, Ko, Bao-Tsan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959767/
https://www.ncbi.nlm.nih.gov/pubmed/21580877
http://dx.doi.org/10.1107/S1600536808033114
Descripción
Sumario:The Cu(II) atom in the title complex, [Cu(C(18)H(21)N(2)O(2))(C(2)H(3)O(2))], is tetra­coordinated by two N atoms and two O atoms, of which one O atom is attributed to the acetate group and the other atoms are from the tridentate salicylideneiminate ligand, forming a slight distorted square-planar environment. The other acetate O atom exhibits a very weak intra­molecular inter­action toward the Cu atom, the Cu—O distance of 2.771 (2) Å being shorter than the van der Waals radii for Cu and O atoms (2.92 Å). Furthermore, there are weak inter­molecular inter­actions, in which the bonding O atom of the acetate group can bridge to the Cu atom of another complex, and the distance of 2.523 (2) Å is about 0.4 Å shorter than the van der Waals Cu—O distance in other crystal structures.