Bis{2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) N,O}cobalt(II)

In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolate ligands, displaying a distorted tetra­hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis a...

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Detalles Bibliográficos
Autores principales: Jiang, Wei, Mo, Gui-Di, Jin, Lie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959770/
https://www.ncbi.nlm.nih.gov/pubmed/21580845
http://dx.doi.org/10.1107/S1600536808032303
Descripción
Sumario:In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolate ligands, displaying a distorted tetra­hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol­ecular symmetry of the complex is C (2). The two phenolate rings are perpendicular [89.8 (3)°].

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