Bis{2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) N,O}cobalt(II)

In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolate ligands, displaying a distorted tetra­hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis a...

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Detalles Bibliográficos
Autores principales: Jiang, Wei, Mo, Gui-Di, Jin, Lie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959770/
https://www.ncbi.nlm.nih.gov/pubmed/21580845
http://dx.doi.org/10.1107/S1600536808032303
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author Jiang, Wei
Mo, Gui-Di
Jin, Lie
author_facet Jiang, Wei
Mo, Gui-Di
Jin, Lie
author_sort Jiang, Wei
collection PubMed
description In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolate ligands, displaying a distorted tetra­hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol­ecular symmetry of the complex is C (2). The two phenolate rings are perpendicular [89.8 (3)°].
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spelling pubmed-29597702010-12-30 Bis{2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) N,O}cobalt(II) Jiang, Wei Mo, Gui-Di Jin, Lie Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(14)H(10)Br(2)NO)(2)], the Co(II) ion is coordinated by an O and an N atom from two equivalent 2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolate ligands, displaying a distorted tetra­hedral geometry. The Co(II) ion occupies a special position on a twofold rotation axis and thus the mol­ecular symmetry of the complex is C (2). The two phenolate rings are perpendicular [89.8 (3)°]. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959770/ /pubmed/21580845 http://dx.doi.org/10.1107/S1600536808032303 Text en © Jiang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jiang, Wei
Mo, Gui-Di
Jin, Lie
Bis{2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) N,O}cobalt(II)
title Bis{2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) N,O}cobalt(II)
title_full Bis{2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) N,O}cobalt(II)
title_fullStr Bis{2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) N,O}cobalt(II)
title_full_unstemmed Bis{2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) N,O}cobalt(II)
title_short Bis{2-[(E)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) N,O}cobalt(II)
title_sort bis{2-[(e)-benzyl­imino­meth­yl]-4,6-dibromo­phenolato-κ(2) n,o}cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959770/
https://www.ncbi.nlm.nih.gov/pubmed/21580845
http://dx.doi.org/10.1107/S1600536808032303
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AT moguidi bis2ebenzyliminomethyl46dibromophenolatok2nocobaltii
AT jinlie bis2ebenzyliminomethyl46dibromophenolatok2nocobaltii

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