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(E)-Methyl N′-(2-furylmethylene)hydrazinecarboxylate
The title compound, C(7)H(8)N(2)O(3), crystallizes with two independent but essentially identical molecules in the asymmetric unit. Each molecule adopts a trans configuration with respect to the C=N bond. The hydrazinecarboxylate group is twisted from the furan ring by 7.78 (13)° in one molecule...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959771/ https://www.ncbi.nlm.nih.gov/pubmed/21581006 http://dx.doi.org/10.1107/S1600536808033825 |
| _version_ | 1782188579512909824 |
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| author | Lv, Lu-Ping Zhang, Yong-Zhao Ding, Xiao-Min Yu, Wen-Bo Hu, Xian-Chao |
| author_facet | Lv, Lu-Ping Zhang, Yong-Zhao Ding, Xiao-Min Yu, Wen-Bo Hu, Xian-Chao |
| author_sort | Lv, Lu-Ping |
| collection | PubMed |
| description | The title compound, C(7)H(8)N(2)O(3), crystallizes with two independent but essentially identical molecules in the asymmetric unit. Each molecule adopts a trans configuration with respect to the C=N bond. The hydrazinecarboxylate group is twisted from the furan ring by 7.78 (13)° in one molecule and by 7.01 (17)° in the other. In the crystal structure, molecules are linked into chains running along [010] by bifurcated N—H⋯(N,O) and N—H⋯O hydrogen bonds. In addition, weak C—H⋯O interactions and an O⋯C short contact [2.896 (3) Å] are observed. |
| format | Text |
| id | pubmed-2959771 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29597712010-12-30 (E)-Methyl N′-(2-furylmethylene)hydrazinecarboxylate Lv, Lu-Ping Zhang, Yong-Zhao Ding, Xiao-Min Yu, Wen-Bo Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(7)H(8)N(2)O(3), crystallizes with two independent but essentially identical molecules in the asymmetric unit. Each molecule adopts a trans configuration with respect to the C=N bond. The hydrazinecarboxylate group is twisted from the furan ring by 7.78 (13)° in one molecule and by 7.01 (17)° in the other. In the crystal structure, molecules are linked into chains running along [010] by bifurcated N—H⋯(N,O) and N—H⋯O hydrogen bonds. In addition, weak C—H⋯O interactions and an O⋯C short contact [2.896 (3) Å] are observed. International Union of Crystallography 2008-10-22 /pmc/articles/PMC2959771/ /pubmed/21581006 http://dx.doi.org/10.1107/S1600536808033825 Text en © Lv et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Lv, Lu-Ping Zhang, Yong-Zhao Ding, Xiao-Min Yu, Wen-Bo Hu, Xian-Chao (E)-Methyl N′-(2-furylmethylene)hydrazinecarboxylate |
| title | (E)-Methyl N′-(2-furylmethylene)hydrazinecarboxylate |
| title_full | (E)-Methyl N′-(2-furylmethylene)hydrazinecarboxylate |
| title_fullStr | (E)-Methyl N′-(2-furylmethylene)hydrazinecarboxylate |
| title_full_unstemmed | (E)-Methyl N′-(2-furylmethylene)hydrazinecarboxylate |
| title_short | (E)-Methyl N′-(2-furylmethylene)hydrazinecarboxylate |
| title_sort | (e)-methyl n′-(2-furylmethylene)hydrazinecarboxylate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959771/ https://www.ncbi.nlm.nih.gov/pubmed/21581006 http://dx.doi.org/10.1107/S1600536808033825 |
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