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catena-Poly[[[2,6-bis(pyrazol-1-yl-κN (2))pyridine-κN (1)](nitrato-κ(2) O,O′)cadmium(II)]-μ-thiocyanato-κ(2) N:S]
In the title crystal structure, [Cd(NCS)(NO(3))(C(11)H(9)N(5))](n), the unique Cd(II) ion is coordinated in a distorted pentagonal–bipyramidal environment. The axial thiocyanate ligands act in a μ(1,3)-bridging mode to connect symmetry-related Cd(II) ions into one-dimensional chains along [010]. I...
| Autores principales: | , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959772/ https://www.ncbi.nlm.nih.gov/pubmed/21580839 http://dx.doi.org/10.1107/S1600536808032297 |
| _version_ | 1782188579747790848 |
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| author | Yang, Zhong Nian Sun, Ting Ting |
| author_facet | Yang, Zhong Nian Sun, Ting Ting |
| author_sort | Yang, Zhong Nian |
| collection | PubMed |
| description | In the title crystal structure, [Cd(NCS)(NO(3))(C(11)H(9)N(5))](n), the unique Cd(II) ion is coordinated in a distorted pentagonal–bipyramidal environment. The axial thiocyanate ligands act in a μ(1,3)-bridging mode to connect symmetry-related Cd(II) ions into one-dimensional chains along [010]. In addition, there are intermolecular C—H⋯O contacts between chains. |
| format | Text |
| id | pubmed-2959772 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29597722010-12-30 catena-Poly[[[2,6-bis(pyrazol-1-yl-κN (2))pyridine-κN (1)](nitrato-κ(2) O,O′)cadmium(II)]-μ-thiocyanato-κ(2) N:S] Yang, Zhong Nian Sun, Ting Ting Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title crystal structure, [Cd(NCS)(NO(3))(C(11)H(9)N(5))](n), the unique Cd(II) ion is coordinated in a distorted pentagonal–bipyramidal environment. The axial thiocyanate ligands act in a μ(1,3)-bridging mode to connect symmetry-related Cd(II) ions into one-dimensional chains along [010]. In addition, there are intermolecular C—H⋯O contacts between chains. International Union of Crystallography 2008-10-11 /pmc/articles/PMC2959772/ /pubmed/21580839 http://dx.doi.org/10.1107/S1600536808032297 Text en © Yang and Sun 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Yang, Zhong Nian Sun, Ting Ting catena-Poly[[[2,6-bis(pyrazol-1-yl-κN (2))pyridine-κN (1)](nitrato-κ(2) O,O′)cadmium(II)]-μ-thiocyanato-κ(2) N:S] |
| title |
catena-Poly[[[2,6-bis(pyrazol-1-yl-κN
(2))pyridine-κN
(1)](nitrato-κ(2)
O,O′)cadmium(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_full |
catena-Poly[[[2,6-bis(pyrazol-1-yl-κN
(2))pyridine-κN
(1)](nitrato-κ(2)
O,O′)cadmium(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_fullStr |
catena-Poly[[[2,6-bis(pyrazol-1-yl-κN
(2))pyridine-κN
(1)](nitrato-κ(2)
O,O′)cadmium(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_full_unstemmed |
catena-Poly[[[2,6-bis(pyrazol-1-yl-κN
(2))pyridine-κN
(1)](nitrato-κ(2)
O,O′)cadmium(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_short |
catena-Poly[[[2,6-bis(pyrazol-1-yl-κN
(2))pyridine-κN
(1)](nitrato-κ(2)
O,O′)cadmium(II)]-μ-thiocyanato-κ(2)
N:S] |
| title_sort | catena-poly[[[2,6-bis(pyrazol-1-yl-κn
(2))pyridine-κn
(1)](nitrato-κ(2)
o,o′)cadmium(ii)]-μ-thiocyanato-κ(2)
n:s] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959772/ https://www.ncbi.nlm.nih.gov/pubmed/21580839 http://dx.doi.org/10.1107/S1600536808032297 |
| work_keys_str_mv | AT yangzhongnian catenapoly26bispyrazol1ylkn2pyridinekn1nitratok2oocadmiumiimthiocyanatok2ns AT suntingting catenapoly26bispyrazol1ylkn2pyridinekn1nitratok2oocadmiumiimthiocyanatok2ns |