[N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(II) dinitrate dihydrate

In the title compound, [Ni(C(38)H(38)N(10))](NO(3))(2)·2H(2)O, the Ni(II) ion is located on a crystallographic twofold rotation axis and is in a distorted octa­hedral coordination environment. The crystal structure is stablized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, and weak C—H⋯π inter­...

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Detalles Bibliográficos
Autores principales: Zhan, Dan, Xiao, Zuo-An
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959773/
https://www.ncbi.nlm.nih.gov/pubmed/21580822
http://dx.doi.org/10.1107/S1600536808031553
Descripción
Sumario:In the title compound, [Ni(C(38)H(38)N(10))](NO(3))(2)·2H(2)O, the Ni(II) ion is located on a crystallographic twofold rotation axis and is in a distorted octa­hedral coordination environment. The crystal structure is stablized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, and weak C—H⋯π inter­actions. The O atoms of the unique nitrate ion are disordered over two sites with occupancies of 0.63 (1) and 0.37 (1). In addition, the O atom of the unique solvent water mol­ecule is disorded over two sites with equal occupancies.

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