[N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(II) dinitrate dihydrate

In the title compound, [Ni(C(38)H(38)N(10))](NO(3))(2)·2H(2)O, the Ni(II) ion is located on a crystallographic twofold rotation axis and is in a distorted octa­hedral coordination environment. The crystal structure is stablized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, and weak C—H⋯π inter­...

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Detalles Bibliográficos
Autores principales: Zhan, Dan, Xiao, Zuo-An
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959773/
https://www.ncbi.nlm.nih.gov/pubmed/21580822
http://dx.doi.org/10.1107/S1600536808031553
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author Zhan, Dan
Xiao, Zuo-An
author_facet Zhan, Dan
Xiao, Zuo-An
author_sort Zhan, Dan
collection PubMed
description In the title compound, [Ni(C(38)H(38)N(10))](NO(3))(2)·2H(2)O, the Ni(II) ion is located on a crystallographic twofold rotation axis and is in a distorted octa­hedral coordination environment. The crystal structure is stablized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, and weak C—H⋯π inter­actions. The O atoms of the unique nitrate ion are disordered over two sites with occupancies of 0.63 (1) and 0.37 (1). In addition, the O atom of the unique solvent water mol­ecule is disorded over two sites with equal occupancies.
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spelling pubmed-29597732010-12-30 [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(II) dinitrate dihydrate Zhan, Dan Xiao, Zuo-An Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(38)H(38)N(10))](NO(3))(2)·2H(2)O, the Ni(II) ion is located on a crystallographic twofold rotation axis and is in a distorted octa­hedral coordination environment. The crystal structure is stablized by inter­molecular N—H⋯O and C—H⋯O hydrogen bonds, and weak C—H⋯π inter­actions. The O atoms of the unique nitrate ion are disordered over two sites with occupancies of 0.63 (1) and 0.37 (1). In addition, the O atom of the unique solvent water mol­ecule is disorded over two sites with equal occupancies. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959773/ /pubmed/21580822 http://dx.doi.org/10.1107/S1600536808031553 Text en © Zhan and Xiao 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhan, Dan
Xiao, Zuo-An
[N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(II) dinitrate dihydrate
title [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(II) dinitrate dihydrate
title_full [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(II) dinitrate dihydrate
title_fullStr [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(II) dinitrate dihydrate
title_full_unstemmed [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(II) dinitrate dihydrate
title_short [N,N,N′,N′-Tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(II) dinitrate dihydrate
title_sort [n,n,n′,n′-tetra­kis(benzimidazol-2-yl­meth­yl)cyclo­hexane-1,2-diamine]­nickel(ii) dinitrate dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959773/
https://www.ncbi.nlm.nih.gov/pubmed/21580822
http://dx.doi.org/10.1107/S1600536808031553
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