(Z,Z)-1,4-Diiodo-1,4-bis­(trimethyl­silyl)buta-1,3-diene

The asymmetric unit of the title compound, C(10)H(20)I(2)Si(2), contains two half-mol­ecules. Both complete molecules are generated by crystallographic inversion centers located at the mid-points of the central C—C single bonds; the butadiene groups are planar, with a trans conformation about the ce...

Descripción completa

Detalles Bibliográficos
Autores principales: Bats, Jan W., Urschel, Birgit, Müller, Thomas
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959778/
https://www.ncbi.nlm.nih.gov/pubmed/21581089
http://dx.doi.org/10.1107/S160053680803482X
_version_ 1782188581150785536
author Bats, Jan W.
Urschel, Birgit
Müller, Thomas
author_facet Bats, Jan W.
Urschel, Birgit
Müller, Thomas
author_sort Bats, Jan W.
collection PubMed
description The asymmetric unit of the title compound, C(10)H(20)I(2)Si(2), contains two half-mol­ecules. Both complete molecules are generated by crystallographic inversion centers located at the mid-points of the central C—C single bonds; the butadiene groups are planar, with a trans conformation about the central C—C bond. The mol­ecules show short intra­molecular H⋯I contacts of 2.89 and 2.92 Å. The crystal packing shows no short inter­molecular contacts.
format Text
id pubmed-2959778
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29597782010-12-30 (Z,Z)-1,4-Diiodo-1,4-bis­(trimethyl­silyl)buta-1,3-diene Bats, Jan W. Urschel, Birgit Müller, Thomas Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(10)H(20)I(2)Si(2), contains two half-mol­ecules. Both complete molecules are generated by crystallographic inversion centers located at the mid-points of the central C—C single bonds; the butadiene groups are planar, with a trans conformation about the central C—C bond. The mol­ecules show short intra­molecular H⋯I contacts of 2.89 and 2.92 Å. The crystal packing shows no short inter­molecular contacts. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959778/ /pubmed/21581089 http://dx.doi.org/10.1107/S160053680803482X Text en © Bats et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bats, Jan W.
Urschel, Birgit
Müller, Thomas
(Z,Z)-1,4-Diiodo-1,4-bis­(trimethyl­silyl)buta-1,3-diene
title (Z,Z)-1,4-Diiodo-1,4-bis­(trimethyl­silyl)buta-1,3-diene
title_full (Z,Z)-1,4-Diiodo-1,4-bis­(trimethyl­silyl)buta-1,3-diene
title_fullStr (Z,Z)-1,4-Diiodo-1,4-bis­(trimethyl­silyl)buta-1,3-diene
title_full_unstemmed (Z,Z)-1,4-Diiodo-1,4-bis­(trimethyl­silyl)buta-1,3-diene
title_short (Z,Z)-1,4-Diiodo-1,4-bis­(trimethyl­silyl)buta-1,3-diene
title_sort (z,z)-1,4-diiodo-1,4-bis­(trimethyl­silyl)buta-1,3-diene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959778/
https://www.ncbi.nlm.nih.gov/pubmed/21581089
http://dx.doi.org/10.1107/S160053680803482X
work_keys_str_mv AT batsjanw zz14diiodo14bistrimethylsilylbuta13diene
AT urschelbirgit zz14diiodo14bistrimethylsilylbuta13diene
AT mullerthomas zz14diiodo14bistrimethylsilylbuta13diene

Ejemplares similares