catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] bis­(perchlorate) 4,4′-bipyridine disolvate dihydrate]

In the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](ClO(4))(2)·2C(10)H(8)N(2)·2H(2)O}(n), slightly distorted octa­hedrally coordinated Co(II) ions situated on inversion centers are linked into polycationic chains through 4,4′-bipyridine tethering ligands. These are connected into supra­molecular l...

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Detalles Bibliográficos
Autores principales: Nettleman, Joseph H., LaDuca, Robert L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959782/
https://www.ncbi.nlm.nih.gov/pubmed/21580916
http://dx.doi.org/10.1107/S1600536808035125
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author Nettleman, Joseph H.
LaDuca, Robert L.
author_facet Nettleman, Joseph H.
LaDuca, Robert L.
author_sort Nettleman, Joseph H.
collection PubMed
description In the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](ClO(4))(2)·2C(10)H(8)N(2)·2H(2)O}(n), slightly distorted octa­hedrally coordinated Co(II) ions situated on inversion centers are linked into polycationic chains through 4,4′-bipyridine tethering ligands. These are connected into supra­molecular layers by hydrogen bonding involving aqua ligands, perchlorate anions and uncoordinated water mol­ecules. A twofold inter­penetrated primitive cubic supra­molecular network is formed by the inter­action of pseudo-layers by hydrogen bonding between aqua ligands and unligated 4,4′-bipyridine mol­ecules.
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spelling pubmed-29597822010-12-30 catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] bis­(perchlorate) 4,4′-bipyridine disolvate dihydrate] Nettleman, Joseph H. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Co(C(10)H(8)N(2))(H(2)O)(4)](ClO(4))(2)·2C(10)H(8)N(2)·2H(2)O}(n), slightly distorted octa­hedrally coordinated Co(II) ions situated on inversion centers are linked into polycationic chains through 4,4′-bipyridine tethering ligands. These are connected into supra­molecular layers by hydrogen bonding involving aqua ligands, perchlorate anions and uncoordinated water mol­ecules. A twofold inter­penetrated primitive cubic supra­molecular network is formed by the inter­action of pseudo-layers by hydrogen bonding between aqua ligands and unligated 4,4′-bipyridine mol­ecules. International Union of Crystallography 2008-10-31 /pmc/articles/PMC2959782/ /pubmed/21580916 http://dx.doi.org/10.1107/S1600536808035125 Text en © Nettleman and LaDuca 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nettleman, Joseph H.
LaDuca, Robert L.
catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] bis­(perchlorate) 4,4′-bipyridine disolvate dihydrate]
title catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] bis­(perchlorate) 4,4′-bipyridine disolvate dihydrate]
title_full catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] bis­(perchlorate) 4,4′-bipyridine disolvate dihydrate]
title_fullStr catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] bis­(perchlorate) 4,4′-bipyridine disolvate dihydrate]
title_full_unstemmed catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] bis­(perchlorate) 4,4′-bipyridine disolvate dihydrate]
title_short catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] bis­(perchlorate) 4,4′-bipyridine disolvate dihydrate]
title_sort catena-poly[[[tetra­aqua­cobalt(ii)]-μ-4,4′-bipyridine-κ(2) n:n′] bis­(perchlorate) 4,4′-bipyridine disolvate dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959782/
https://www.ncbi.nlm.nih.gov/pubmed/21580916
http://dx.doi.org/10.1107/S1600536808035125
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AT laducarobertl catenapolytetraaquacobaltiim44bipyridinek2nnbisperchlorate44bipyridinedisolvatedihydrate

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