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catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine]
In the title compound, [Co(C(9)H(5)O(6))(2)(C(10)H(8)N(2))](n), the asymmetric unit consists of one Co(2+) ion with site symmetry 2, one mono-deprotonated 1,3,5-benzenetricarboxylic acid anion and one-half of a 4,4′-bipyridine (4,4′-bipy) molecule, in which two N and two C atoms have site symmetry...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959783/ https://www.ncbi.nlm.nih.gov/pubmed/21580850 http://dx.doi.org/10.1107/S1600536808032558 |
Sumario: | In the title compound, [Co(C(9)H(5)O(6))(2)(C(10)H(8)N(2))](n), the asymmetric unit consists of one Co(2+) ion with site symmetry 2, one mono-deprotonated 1,3,5-benzenetricarboxylic acid anion and one-half of a 4,4′-bipyridine (4,4′-bipy) molecule, in which two N and two C atoms have site symmetry 2. In the crystal structure, the Co(2+) centre is coordinated by four O atoms from two bidentate carboxylate groups of two anions and two N atoms of two 4,4′-bipy molecules, resulting in infinite chains propagating in [010]. The cobalt coordination is distorted trans-CoO(4)N(2) octahedral and interchain O—H⋯O hydrogen bonds complete the structure. |
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