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catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine]
In the title compound, [Co(C(9)H(5)O(6))(2)(C(10)H(8)N(2))](n), the asymmetric unit consists of one Co(2+) ion with site symmetry 2, one mono-deprotonated 1,3,5-benzenetricarboxylic acid anion and one-half of a 4,4′-bipyridine (4,4′-bipy) molecule, in which two N and two C atoms have site symmetry...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959783/ https://www.ncbi.nlm.nih.gov/pubmed/21580850 http://dx.doi.org/10.1107/S1600536808032558 |
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author | Ling, Chun-Sheng Han, Qiu-Xia |
author_facet | Ling, Chun-Sheng Han, Qiu-Xia |
author_sort | Ling, Chun-Sheng |
collection | PubMed |
description | In the title compound, [Co(C(9)H(5)O(6))(2)(C(10)H(8)N(2))](n), the asymmetric unit consists of one Co(2+) ion with site symmetry 2, one mono-deprotonated 1,3,5-benzenetricarboxylic acid anion and one-half of a 4,4′-bipyridine (4,4′-bipy) molecule, in which two N and two C atoms have site symmetry 2. In the crystal structure, the Co(2+) centre is coordinated by four O atoms from two bidentate carboxylate groups of two anions and two N atoms of two 4,4′-bipy molecules, resulting in infinite chains propagating in [010]. The cobalt coordination is distorted trans-CoO(4)N(2) octahedral and interchain O—H⋯O hydrogen bonds complete the structure. |
format | Text |
id | pubmed-2959783 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29597832010-12-30 catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine] Ling, Chun-Sheng Han, Qiu-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(9)H(5)O(6))(2)(C(10)H(8)N(2))](n), the asymmetric unit consists of one Co(2+) ion with site symmetry 2, one mono-deprotonated 1,3,5-benzenetricarboxylic acid anion and one-half of a 4,4′-bipyridine (4,4′-bipy) molecule, in which two N and two C atoms have site symmetry 2. In the crystal structure, the Co(2+) centre is coordinated by four O atoms from two bidentate carboxylate groups of two anions and two N atoms of two 4,4′-bipy molecules, resulting in infinite chains propagating in [010]. The cobalt coordination is distorted trans-CoO(4)N(2) octahedral and interchain O—H⋯O hydrogen bonds complete the structure. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959783/ /pubmed/21580850 http://dx.doi.org/10.1107/S1600536808032558 Text en © Ling and Han 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Ling, Chun-Sheng Han, Qiu-Xia catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine] |
title |
catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine] |
title_full |
catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine] |
title_fullStr |
catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine] |
title_full_unstemmed |
catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine] |
title_short |
catena-Poly[[bis(3,5-dicarboxybenzoato)cobalt(II)]-μ-4,4′-bipyridine] |
title_sort | catena-poly[[bis(3,5-dicarboxybenzoato)cobalt(ii)]-μ-4,4′-bipyridine] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959783/ https://www.ncbi.nlm.nih.gov/pubmed/21580850 http://dx.doi.org/10.1107/S1600536808032558 |
work_keys_str_mv | AT lingchunsheng catenapolybis35dicarboxybenzoatocobaltiim44bipyridine AT hanqiuxia catenapolybis35dicarboxybenzoatocobaltiim44bipyridine |