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catena-Poly[[bis­(3,5-dicarboxy­benzo­ato)cobalt(II)]-μ-4,4′-bipyridine]

In the title compound, [Co(C(9)H(5)O(6))(2)(C(10)H(8)N(2))](n), the asymmetric unit consists of one Co(2+) ion with site symmetry 2, one mono-deprotonated 1,3,5-benzene­tricarboxylic acid anion and one-half of a 4,4′-bipyridine (4,4′-bipy) mol­ecule, in which two N and two C atoms have site symmetry...

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Detalles Bibliográficos
Autores principales: Ling, Chun-Sheng, Han, Qiu-Xia
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959783/
https://www.ncbi.nlm.nih.gov/pubmed/21580850
http://dx.doi.org/10.1107/S1600536808032558
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author Ling, Chun-Sheng
Han, Qiu-Xia
author_facet Ling, Chun-Sheng
Han, Qiu-Xia
author_sort Ling, Chun-Sheng
collection PubMed
description In the title compound, [Co(C(9)H(5)O(6))(2)(C(10)H(8)N(2))](n), the asymmetric unit consists of one Co(2+) ion with site symmetry 2, one mono-deprotonated 1,3,5-benzene­tricarboxylic acid anion and one-half of a 4,4′-bipyridine (4,4′-bipy) mol­ecule, in which two N and two C atoms have site symmetry 2. In the crystal structure, the Co(2+) centre is coordinated by four O atoms from two bidentate carboxyl­ate groups of two anions and two N atoms of two 4,4′-bipy mol­ecules, resulting in infinite chains propagating in [010]. The cobalt coordination is distorted trans-CoO(4)N(2) octa­hedral and inter­chain O—H⋯O hydrogen bonds complete the structure.
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spelling pubmed-29597832010-12-30 catena-Poly[[bis­(3,5-dicarboxy­benzo­ato)cobalt(II)]-μ-4,4′-bipyridine] Ling, Chun-Sheng Han, Qiu-Xia Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(9)H(5)O(6))(2)(C(10)H(8)N(2))](n), the asymmetric unit consists of one Co(2+) ion with site symmetry 2, one mono-deprotonated 1,3,5-benzene­tricarboxylic acid anion and one-half of a 4,4′-bipyridine (4,4′-bipy) mol­ecule, in which two N and two C atoms have site symmetry 2. In the crystal structure, the Co(2+) centre is coordinated by four O atoms from two bidentate carboxyl­ate groups of two anions and two N atoms of two 4,4′-bipy mol­ecules, resulting in infinite chains propagating in [010]. The cobalt coordination is distorted trans-CoO(4)N(2) octa­hedral and inter­chain O—H⋯O hydrogen bonds complete the structure. International Union of Crystallography 2008-10-15 /pmc/articles/PMC2959783/ /pubmed/21580850 http://dx.doi.org/10.1107/S1600536808032558 Text en © Ling and Han 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ling, Chun-Sheng
Han, Qiu-Xia
catena-Poly[[bis­(3,5-dicarboxy­benzo­ato)cobalt(II)]-μ-4,4′-bipyridine]
title catena-Poly[[bis­(3,5-dicarboxy­benzo­ato)cobalt(II)]-μ-4,4′-bipyridine]
title_full catena-Poly[[bis­(3,5-dicarboxy­benzo­ato)cobalt(II)]-μ-4,4′-bipyridine]
title_fullStr catena-Poly[[bis­(3,5-dicarboxy­benzo­ato)cobalt(II)]-μ-4,4′-bipyridine]
title_full_unstemmed catena-Poly[[bis­(3,5-dicarboxy­benzo­ato)cobalt(II)]-μ-4,4′-bipyridine]
title_short catena-Poly[[bis­(3,5-dicarboxy­benzo­ato)cobalt(II)]-μ-4,4′-bipyridine]
title_sort catena-poly[[bis­(3,5-dicarboxy­benzo­ato)cobalt(ii)]-μ-4,4′-bipyridine]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959783/
https://www.ncbi.nlm.nih.gov/pubmed/21580850
http://dx.doi.org/10.1107/S1600536808032558
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