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Tetrakis(μ-naphthalene-1-acetato-1:2κ(2) O:O′)bis(naphthalene-1-acetato)-1κ(2) O,O′;2κ(2) O,O′-bis(1,10-phenanthroline)-1κ(2) N,N′;2κ(2) N,N′-europium(III)samarium(III)
In the title compound, [EuSm(C(12)H(9)O(2))(6)(C(12)H(8)N(2))(2)], the metal site is statistically occupied (50:50) by Eu and Sm atoms, forming a centrosymmetric complex. The metal site is nine-coordinate, in a distorted monocapped square-antiprismatic coordination geometry. Molecules are linked i...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959786/ https://www.ncbi.nlm.nih.gov/pubmed/21580865 http://dx.doi.org/10.1107/S1600536808032960 |
| _version_ | 1782188583092748288 |
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| author | Xia, Hai-Tao Liu, Yu-Fen Chen, Liang Wang, Da-Qi |
| author_facet | Xia, Hai-Tao Liu, Yu-Fen Chen, Liang Wang, Da-Qi |
| author_sort | Xia, Hai-Tao |
| collection | PubMed |
| description | In the title compound, [EuSm(C(12)H(9)O(2))(6)(C(12)H(8)N(2))(2)], the metal site is statistically occupied (50:50) by Eu and Sm atoms, forming a centrosymmetric complex. The metal site is nine-coordinate, in a distorted monocapped square-antiprismatic coordination geometry. Molecules are linked into three chains by C—H⋯π interactions and C—H⋯O hydrogen bonds. The combination of these chains generates a three-dimensional framework structure. One of the bridging naphthalene-1-acetate ligands was found to be disordered over two sites; the site occupancies for the naphthylmethyl group refined to 0.628 (14) and 0.372 (14). |
| format | Text |
| id | pubmed-2959786 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29597862010-12-30 Tetrakis(μ-naphthalene-1-acetato-1:2κ(2) O:O′)bis(naphthalene-1-acetato)-1κ(2) O,O′;2κ(2) O,O′-bis(1,10-phenanthroline)-1κ(2) N,N′;2κ(2) N,N′-europium(III)samarium(III) Xia, Hai-Tao Liu, Yu-Fen Chen, Liang Wang, Da-Qi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [EuSm(C(12)H(9)O(2))(6)(C(12)H(8)N(2))(2)], the metal site is statistically occupied (50:50) by Eu and Sm atoms, forming a centrosymmetric complex. The metal site is nine-coordinate, in a distorted monocapped square-antiprismatic coordination geometry. Molecules are linked into three chains by C—H⋯π interactions and C—H⋯O hydrogen bonds. The combination of these chains generates a three-dimensional framework structure. One of the bridging naphthalene-1-acetate ligands was found to be disordered over two sites; the site occupancies for the naphthylmethyl group refined to 0.628 (14) and 0.372 (14). International Union of Crystallography 2008-10-18 /pmc/articles/PMC2959786/ /pubmed/21580865 http://dx.doi.org/10.1107/S1600536808032960 Text en © Xia et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xia, Hai-Tao Liu, Yu-Fen Chen, Liang Wang, Da-Qi Tetrakis(μ-naphthalene-1-acetato-1:2κ(2) O:O′)bis(naphthalene-1-acetato)-1κ(2) O,O′;2κ(2) O,O′-bis(1,10-phenanthroline)-1κ(2) N,N′;2κ(2) N,N′-europium(III)samarium(III) |
| title | Tetrakis(μ-naphthalene-1-acetato-1:2κ(2)
O:O′)bis(naphthalene-1-acetato)-1κ(2)
O,O′;2κ(2)
O,O′-bis(1,10-phenanthroline)-1κ(2)
N,N′;2κ(2)
N,N′-europium(III)samarium(III) |
| title_full | Tetrakis(μ-naphthalene-1-acetato-1:2κ(2)
O:O′)bis(naphthalene-1-acetato)-1κ(2)
O,O′;2κ(2)
O,O′-bis(1,10-phenanthroline)-1κ(2)
N,N′;2κ(2)
N,N′-europium(III)samarium(III) |
| title_fullStr | Tetrakis(μ-naphthalene-1-acetato-1:2κ(2)
O:O′)bis(naphthalene-1-acetato)-1κ(2)
O,O′;2κ(2)
O,O′-bis(1,10-phenanthroline)-1κ(2)
N,N′;2κ(2)
N,N′-europium(III)samarium(III) |
| title_full_unstemmed | Tetrakis(μ-naphthalene-1-acetato-1:2κ(2)
O:O′)bis(naphthalene-1-acetato)-1κ(2)
O,O′;2κ(2)
O,O′-bis(1,10-phenanthroline)-1κ(2)
N,N′;2κ(2)
N,N′-europium(III)samarium(III) |
| title_short | Tetrakis(μ-naphthalene-1-acetato-1:2κ(2)
O:O′)bis(naphthalene-1-acetato)-1κ(2)
O,O′;2κ(2)
O,O′-bis(1,10-phenanthroline)-1κ(2)
N,N′;2κ(2)
N,N′-europium(III)samarium(III) |
| title_sort | tetrakis(μ-naphthalene-1-acetato-1:2κ(2)
o:o′)bis(naphthalene-1-acetato)-1κ(2)
o,o′;2κ(2)
o,o′-bis(1,10-phenanthroline)-1κ(2)
n,n′;2κ(2)
n,n′-europium(iii)samarium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959786/ https://www.ncbi.nlm.nih.gov/pubmed/21580865 http://dx.doi.org/10.1107/S1600536808032960 |
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