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A one-dimensional Ag(I) coordination polymer: catena-poly[[[[N′-(4-cyanobenzylidene)nicotinohydrazide]silver(I)]-μ-N′-(4-cyanobenzylidene)nicotinohydrazide] trifluoromethanesulfonate]
In the title compound, {[Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3)}(n), the unique Ag(I) ion is coordinated by two N atoms from two pyridine rings of two independent N′-(4-cyanobenzylidene)nicotinohydrazide ligands and one N atom of a carbonitrile group of a symmetry-related N′-(4-cyanobenzylidene)nicot...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959788/ https://www.ncbi.nlm.nih.gov/pubmed/21580906 http://dx.doi.org/10.1107/S1600536808034685 |
Sumario: | In the title compound, {[Ag(C(14)H(10)N(4)O)(2)]CF(3)SO(3)}(n), the unique Ag(I) ion is coordinated by two N atoms from two pyridine rings of two independent N′-(4-cyanobenzylidene)nicotinohydrazide ligands and one N atom of a carbonitrile group of a symmetry-related N′-(4-cyanobenzylidene)nicotinohydrazide ligand, forming a distorted T-shaped coordination environment. One of the independent ligands acts as a bridge connecting Ag(I) ions, forming chains along the a axis. In the crystal structure, two neighbouring antiparallel chains are connected through N—H⋯O hydrogen bonds. In addition, there are relatively short Ag⋯O contacts of 2.723 (3) Å, which connect the chains into a three-dimensional structure. |
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