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Bis(acetylacetonato-κ(2) O,O′)(methanol-κO)(thiocyanato-κN)manganese(III)
In the title complex, [Mn(C(5)H(7)O(2))(2)(NCS)(CH(4)O)], the Mn(III) atom has a slightly distorted octahedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetylacetonate ligands, while the axial positions are occupied by the N a...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959789/ https://www.ncbi.nlm.nih.gov/pubmed/21580823 http://dx.doi.org/10.1107/S1600536808031589 |
| Sumario: | In the title complex, [Mn(C(5)H(7)O(2))(2)(NCS)(CH(4)O)], the Mn(III) atom has a slightly distorted octahedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetylacetonate ligands, while the axial positions are occupied by the N atom of the thiocyanate anion and the O atom of the methanol molecule. In the crystal structure, complex molecules are linked by an intermolecular O—H⋯S hydrogen bond, forming a chain running along [101]. |
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