Bis(acetyl­acetonato-κ(2) O,O′)(methanol-κO)(thio­cyanato-κN)manganese(III)

In the title complex, [Mn(C(5)H(7)O(2))(2)(NCS)(CH(4)O)], the Mn(III) atom has a slightly distorted octa­hedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetyl­acetonate ligands, while the axial positions are occupied by the N a...

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Detalles Bibliográficos
Autores principales: Meng, Shuang-Ming, Xie, Hai, Fan, Yue-Qin, Guo, Yong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959789/
https://www.ncbi.nlm.nih.gov/pubmed/21580823
http://dx.doi.org/10.1107/S1600536808031589
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author Meng, Shuang-Ming
Xie, Hai
Fan, Yue-Qin
Guo, Yong
author_facet Meng, Shuang-Ming
Xie, Hai
Fan, Yue-Qin
Guo, Yong
author_sort Meng, Shuang-Ming
collection PubMed
description In the title complex, [Mn(C(5)H(7)O(2))(2)(NCS)(CH(4)O)], the Mn(III) atom has a slightly distorted octa­hedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetyl­acetonate ligands, while the axial positions are occupied by the N atom of the thio­cyanate anion and the O atom of the methanol mol­ecule. In the crystal structure, complex mol­ecules are linked by an inter­molecular O—H⋯S hydrogen bond, forming a chain running along [101].
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spelling pubmed-29597892010-12-30 Bis(acetyl­acetonato-κ(2) O,O′)(methanol-κO)(thio­cyanato-κN)manganese(III) Meng, Shuang-Ming Xie, Hai Fan, Yue-Qin Guo, Yong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(5)H(7)O(2))(2)(NCS)(CH(4)O)], the Mn(III) atom has a slightly distorted octa­hedral coordination formed by five O atoms and one N atom. The equatorial positions are occupied by four O atoms of two acetyl­acetonate ligands, while the axial positions are occupied by the N atom of the thio­cyanate anion and the O atom of the methanol mol­ecule. In the crystal structure, complex mol­ecules are linked by an inter­molecular O—H⋯S hydrogen bond, forming a chain running along [101]. International Union of Crystallography 2008-10-04 /pmc/articles/PMC2959789/ /pubmed/21580823 http://dx.doi.org/10.1107/S1600536808031589 Text en © Meng et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Meng, Shuang-Ming
Xie, Hai
Fan, Yue-Qin
Guo, Yong
Bis(acetyl­acetonato-κ(2) O,O′)(methanol-κO)(thio­cyanato-κN)manganese(III)
title Bis(acetyl­acetonato-κ(2) O,O′)(methanol-κO)(thio­cyanato-κN)manganese(III)
title_full Bis(acetyl­acetonato-κ(2) O,O′)(methanol-κO)(thio­cyanato-κN)manganese(III)
title_fullStr Bis(acetyl­acetonato-κ(2) O,O′)(methanol-κO)(thio­cyanato-κN)manganese(III)
title_full_unstemmed Bis(acetyl­acetonato-κ(2) O,O′)(methanol-κO)(thio­cyanato-κN)manganese(III)
title_short Bis(acetyl­acetonato-κ(2) O,O′)(methanol-κO)(thio­cyanato-κN)manganese(III)
title_sort bis(acetyl­acetonato-κ(2) o,o′)(methanol-κo)(thio­cyanato-κn)manganese(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2959789/
https://www.ncbi.nlm.nih.gov/pubmed/21580823
http://dx.doi.org/10.1107/S1600536808031589
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AT xiehai bisacetylacetonatok2oomethanolkothiocyanatoknmanganeseiii
AT fanyueqin bisacetylacetonatok2oomethanolkothiocyanatoknmanganeseiii
AT guoyong bisacetylacetonatok2oomethanolkothiocyanatoknmanganeseiii

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